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4-苯基-2-丁酮与芳香醛和芳香胺的Mannich反应
引用本文:杨大成.4-苯基-2-丁酮与芳香醛和芳香胺的Mannich反应[J].西南师范大学学报(自然科学版),1996(4).
作者姓名:杨大成
作者单位:西南师范大学化学化工学院
摘    要:在催化量浓盐酸作用下,4-苯基-2-丁酮与芳香醛和芳香胺直接发生Mannich反应,生成5-苯基-1-芳基-1-芳胺基-3-戊酮.产率75%~92%.共得到15个新化合物.它们的结构都经元素分析、IR和MS证实.

关 键 词:Mannich反应  Mannich碱  芳香醛  芳香胺  4-苯基-2-丁酮

The mannich reaction of 4-pheny1-2-butanone with aromatic aldehydes and acomatic amines
Yang Dacheng.The mannich reaction of 4-pheny1-2-butanone with aromatic aldehydes and acomatic amines[J].Journal of Southwest China Normal University(Natural Science),1996(4).
Authors:Yang Dacheng
Abstract:pheny1-2-Butanone can react directly with some aromatic aldehydes and aromatic amines to form 5-phenyl-1-Arylamino-3-Pentanone in the Presence of catalytic amount of concentlated by drochloric acid in ethanol soluhon. The yield is 75%-92%. All of these Mannich Bases (I) are new compounds. Their structures were confirmed by IR, MS and elemental analyses.
Keywords:Mannich reaction  Mannich bases  arometic aldehydes  aromatic amines  4-phenyl-2-butanone
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