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红土镍矿微波水热法浸提镍钴
引用本文:赵艳,彭犇,郭敏,张梅. 红土镍矿微波水热法浸提镍钴[J]. 北京科技大学学报, 2012, 34(6): 632-638
作者姓名:赵艳  彭犇  郭敏  张梅
作者单位:1. 北京科技大学钢铁冶金新技术国家重点实验室,北京,100083
2. 中国冶金科工股份有限公司,北京,100038
基金项目:国家自然科学基金资助项目,国家重点基础研究发展计划资助项目,教育部新世纪优秀人才支持计划资助项目
摘    要:采用微波水热盐酸浸出方法对腐泥土型红土镍矿提取镍钴进行了研究,详细探讨了焙烧预处理、微波水热浸出温度和浸出时间对镍钴浸出率的影响.对于300℃焙烧预处理后的红土镍矿,微波水热温度为50℃,浸出时间为1 h时,镍的浸出率高达93.65%,钴的浸出率为87.86%.红土镍矿的微波水热浸出体系与普通水热浸出体系相比,镍和钴的浸出效果更好.研究表明,扩散过程是镍、钴浸出过程的主要限制环节.

关 键 词:红土镍矿  微波加热  水热法  提取      焙烧

Extraction of nickel and cobalt from laterite using a microwave assisted hydrothermal leaching method
ZHAO Yan,PENG Ben,GUO Min,ZHANG Mei. Extraction of nickel and cobalt from laterite using a microwave assisted hydrothermal leaching method[J]. Journal of University of Science and Technology Beijing, 2012, 34(6): 632-638
Authors:ZHAO Yan  PENG Ben  GUO Min  ZHANG Mei
Affiliation:1) 1) State Key Laboratory of Advanced Metallurgy,University of Science and Technology Beijing,Beijing 100083,China 2) China Metallurgical Corporation Ltd.,Beijing 100038,China
Abstract:A microwave assisted hydrothermal leaching method was used to extract nickel and cobalt from saprolite laterite.The effects of roasting pretreatment,leaching temperature and time on the extraction ratios of nickel and cobalt were investigated in detail.The extraction ratio of 93.65% for nickel and 87.86% for cobalt can be obtained respectively when the leaching temperature and time are 50 ℃ and 1h for saprolite laterite only pre-roasted at 300 ℃.Comparing the microwave assisted hydrothermal leaching method with a hydrothermal leaching method,nickel and cobalt can be extracted more efficiently from the laterite.The experimental data indicate that the leaching process of nickel and cobalt is a diffusion-controlled process.
Keywords:laterite  microwave heating  hydrothermal methods  extraction  nickel  cobalt  roasting
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