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高温煤气中HCl气体与脱氯剂的反应动力学
引用本文:豆斌林,高晋生,鲁军,兴沙中. 高温煤气中HCl气体与脱氯剂的反应动力学[J]. 华东理工大学学报(自然科学版), 2000, 26(4): 372-375
作者姓名:豆斌林  高晋生  鲁军  兴沙中
作者单位:华东理工大学能源化工系,上海,200237;华东理工大学能源化工系,上海,200237;华东理工大学能源化工系,上海,200237;华东理工大学能源化工系,上海,200237
基金项目:中国科学院资助项目,国家重点基础研究发展计划(973计划),59776017,G19990221,,
摘    要:在固定床反应器中研究了自制的脱氯剂与高温煤气中HC1气体的反应动力学,得出在550℃时反应受通过产物层的扩散和化学反应反控制,两埂的阻力之比为0.138。同时研究了温度和进口HC1气体浓度对该反应影响,得出反应对于气相HC1为一级反应。

关 键 词:高温煤气  脱氯剂  反应动力学
文章编号:1006-3080(2000)04-0372-04
修稿时间:1999-11-29

Reaction Kinetics of Sorbent for Chloride Removal with HCl in a High-temperature Coal Gas
DOU Bin-lin,GAO Jin-sheng,LU Jun,SHA Xing-zhong. Reaction Kinetics of Sorbent for Chloride Removal with HCl in a High-temperature Coal Gas[J]. Journal of East China University of Science and Technology, 2000, 26(4): 372-375
Authors:DOU Bin-lin  GAO Jin-sheng  LU Jun  SHA Xing-zhong
Affiliation:DOU Bin-lin,GAO Jin-sheng,LU Jun,SHA Xing-zhong(Department of Energy Chemical Engineering ECUST, Shanghai 200237, China)
Abstract:The kinetics of the reaction between the sorbent self prepared and HCl in a gas stream simulating high temperature coal gas was investigated under certain conditions. The experimental results obtained were analyzed by a shinking core model of diffusion and chemical reaction control. The effects of reaction temperature and inlet HCl concentration on reactivity of sorbent were studied in a fixed bed reactor.
Keywords:high-temperature coal gas   sorbent for chloride removal   kinetics of the reaction
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