|
|||||
|
|
| 苯骈15-冠-5催化二溴卡宾与苯乙烯和多芳代苯乙烯环加成反应动力学 | |
| 引用本文： | 林守渊,何英. 苯骈15-冠-5催化二溴卡宾与苯乙烯和多芳代苯乙烯环加成反应动力学[J]. 华东师范大学学报(自然科学版), 1992, 0(2) |
| 作者姓名： | 林守渊 何英 |
| 作者单位： | 华东师范大学化学系(林守渊)，华东师范大学化学系(何英) |
| 摘 要： | 本文研究了在50%NaOH,CH_2Cl_2体系中,苯骈15-冠-5催化产生的二溴卡宾与苯乙烯、多芳代苯乙烯反应的相对速率常数K_(rel),讨论了苯乙烯α及β位上芳基取代基数目和空间位置对K_(rel)的影响. |
| 关 键 词： | 卡宾 苯乙烯环加成反应 反应动力学 |
Reaction Kinetics of the Cycloaddition of Dibrcmocarbene with Styrene and Aryls Substituted Styrene by Benzo-15-crown-5 Catalysis |
|
| LIN SHOUYUAO, HE YING. Reaction Kinetics of the Cycloaddition of Dibrcmocarbene with Styrene and Aryls Substituted Styrene by Benzo-15-crown-5 Catalysis[J]. Journal of East China Normal University(Natural Science), 1992, 0(2) | |
| Authors: | LIN SHOUYUAO HE YING |
| Affiliation: | Department of Chemistry |
| Abstract: | Styrene and aryls substituted styrenes were prepared, and the relative rate constants (K_(rel)) of cycloaddition reaction of these substituted styrenes with dibromocarbene were measured under phase transfer catalysis condition. |
| Keywords: | carbene styrene cycloaddition reaction reaction kinetics |
| 本文献已被 CNKI 等数据库收录！ | |