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激光溅射合成全氯代稠环芳烃
引用本文:周异男,李彩云.激光溅射合成全氯代稠环芳烃[J].河南科学,1999,17(3):246-249.
作者姓名:周异男  李彩云
作者单位:[1]新乡医学院基础部 [2]平原大学化工系
摘    要:用激光溅射多相反应体系,以石墨为固体靶,以四氯化碳为气相和液相反应物,合成了一系列全氯代稠环芳烃化合物。分离和表征了其中的八氯萘、十氯蒽、十氯菲、十氯芘。结果表明,激光溅射这一物理方法可以做为一种有效的合成手段,通过等离子体反应得到产物。

关 键 词:激光溅射  等离子体  合成  全氯代稠环芳烃

Synthesis of perchlorinated polycyclic aromatic hydrocarbon by laser ablation
ZHOU Yi nan\,LI Cai yun\,YAN Fu lin\,GAO Lian zhou\.Synthesis of perchlorinated polycyclic aromatic hydrocarbon by laser ablation[J].Henan Science,1999,17(3):246-249.
Authors:ZHOU Yi nan\  LI Cai yun\  YAN Fu lin\  GAO Lian zhou\
Institution:ZHOU Yi nan\+1,LI Cai yun\+2,YAN Fu lin\+1,GAO Lian zhou\+1
Abstract:By laser ablating a heterogeneous reaction system which was consisted of solid graphite, liquid and gaseous tetrachloromethane, some sorts of perchlorinated polycyclic aromatic hydrocar-bon were synthesized. Among that octachloronaphthalene (C\-\{10\}Cl\-8), decachloroanthracene(C\-\{14\}Cl\-\{10\}), decachlorophenanthrene(C\-\{14\}Cl\-\{10\}) and decachlorofluoranthene(C\-\{16\}Cl\-\{10\}) were separated and chara-cterized. The results in this work indicated that laser ablation as a physical method can be used as a kind of effective synthsis means, various products are obtained by plasma reaction.
Keywords:laser ablation  plasma synthesis  perchlorinated polycyclic aromatic hydrocarbon
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