| 由芳香胺的Mannich碱合成吡唑和吡唑啉类化合物 |
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| 引用本文： | 苏西平,吴永仁.由芳香胺的Mannich碱合成吡唑和吡唑啉类化合物[J].北京师范大学学报(自然科学版),1990(3):70-74. |
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| 作者姓名： | 苏西平 吴永仁 |
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| 作者单位： | 北京师范大学化学系，北京师范大学化学系，北京师范大学化学系 |
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| 摘 要： | 采用芳香胺的Mannich碱亚硝化后再还原、环化的方法制备了3个吡唑类(Ⅳ_(a~c))和11个吡唑啉类(Ⅱ_(a~k))化合物,其中9个是未见报导的新化合物。所有化合物经红外、元素分析确证,对部分化合物的核磁、质谱作了报导。
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| 关 键 词： | 吡唑 吡唑啉 亚硝化 芳香胺 合成 |
STUDIES ON THE APPLICATION OF MANNICH BASE FROM ARYLAMINE IN THE SYNTHESIS OF PYRAZOLES AND PYRAZOLINES |
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| Su Xiping Wu Yongren Yin Chenglie.STUDIES ON THE APPLICATION OF MANNICH BASE FROM ARYLAMINE IN THE SYNTHESIS OF PYRAZOLES AND PYRAZOLINES[J].Journal of Beijing Normal University(Natural Science),1990(3):70-74. |
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| Authors: | Su Xiping Wu Yongren Yin Chenglie |
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| Institution: | Department of Chemistry |
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| Abstract: | Three pyrazoles and eleven pyrazolines are prepared by the reductive cyclization of nitrosated Mannich bases. So far, nine of them have not been reported in the literatures. All these compounds are confirmed by IR and element analysis. The NMR and MS of some of these compounds are given. |
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| Keywords: | pyrazole pyrazoline nitrosation reductive cyclization Mannich base |
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