| 基因转移聚合中的位阻和溶剂效应 |
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| 引用本文： | 邹友思,潘容华.基因转移聚合中的位阻和溶剂效应[J].厦门大学学报(自然科学版),1989,28(1):70-73. |
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| 作者姓名： | 邹友思 潘容华 |
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| 作者单位： | 厦门大学化学系
(邹友思)，厦门大学化学系(潘容华) |
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| 摘 要： | 以二甲基乙烯酮甲基三?基硅氧基缩?为引发剂,二氟化?四乙基铵为催化剂,进行了多种甲基丙烯酸酯和丙烯酸酯的基团转移聚合(GTP),发现甲基丙烯酸酯单体的酯基空间位阻对聚合起阻碍和减速作用,丙烯酸酯单体的酯基空间位则对聚合影响不大,聚甲基丙烯酸甲酯的分子量分布比聚丙烯酸甲酯的窄,溶剂的介电常数和溶剂与聚合物的溶度参数差值的影响聚合速率。
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| 关 键 词： | 基因转移聚合 聚甲基?烯酸酯 聚丙烯酸酯 |
Steric Effect and Solvent Effect in Group Transfer polymerization |
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| Zbu Yousi pan Ronqhua.Steric Effect and Solvent Effect in Group Transfer polymerization[J].Journal of Xiamen University(Natural Science),1989,28(1):70-73. |
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| Authors: | Zbu Yousi pan Ronqhua |
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| Institution: | Dept. of Chem. |
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| Abstract: | Group transfer polymerization ( GTF ) of some methacrylates and acrylates was carried out by using 1-methoxy-1-(trimethylsiloxly)-2-methyl -1-propene (MTS )and Et4 NHF2 as initiator and catalyst, respectively. The rate of GTP decreased with increasing steric hindrance of methacrytates-monomer. Molecular weight distribution of PMA was broader than that of PMMA. The effccts of polarity and solubility parameter of solvent on rate of GTP were all so examined. |
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| Keywords: | Group transfer polymerization Polymethacrylate Polyacrylate |
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