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反相纸层析法分离贵金属的研究
引用本文:王文明.反相纸层析法分离贵金属的研究[J].内蒙古师范大学学报(自然科学版),1989(1).
作者姓名:王文明
作者单位:内蒙古师大化学系
摘    要:本文报导了不同结构的硫醚、亚砜对四种贵金属的反相纸层析行为,考查了硫醚、亚矾的结构对反相纸层析行为的影响,研究表明,在有高沸点溶剂参与固定相的情况下,硫醚、亚砜结构中的电性效应、空间效应均对层析行为产生影响。

关 键 词:反相纸层析  贵金属分离  结构效应

Studies on the Seperation of Noble Metals by Reversed Phase Paper Chromatography
Wang Wenming.Studies on the Seperation of Noble Metals by Reversed Phase Paper Chromatography[J].Journal of Inner Mongolia Normal University(Natural Science Edition),1989(1).
Authors:Wang Wenming
Institution:Department of chemistry
Abstract:The reverse phase chromatographic behaviour of the 4 noble mertals, using paper impregnated with the different structural dialkyl (aryl)sulfides and sulfoxides as stationary phase was reported in this paper.The struc- tural effect of dialkyl (aryl) sulfides and sulfoxides as stationary phase on the reversed phase paper chromatogram of 4 noble matals was investigated. As shown by study the revrsed phase behavior of dialkyl (aryl) sulfides and sulfoxides may be controlled by polar and steric substituents effect under the condition that high boiling point solvent takes part in the stationary phase.
Keywords:Revesed phase paper chromat ogram Seperation of noblematals Structrual effect
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