| 马来二睛基二硫烯过渡金属配合物分子间的弱相互作用 |
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| 引用本文： | 任小明. 马来二睛基二硫烯过渡金属配合物分子间的弱相互作用[J]. 安庆师范学院学报(自然科学版), 2001, 7(2): 23-25,34 |
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| 作者姓名： | 任小明 |
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| 作者单位： | 安庆师范学院,化学系,安徽,安庆,246011 |
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| 摘 要： | 制备并用元素分析、红外光谱表征了两种马来二睛基二硫烯过渡金属配合物。通过测定配合物的单晶结构 ,研究了两种配合物中阳离子间的 π… π或 N O2 … π相互作用。
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| 关 键 词： | Mnt配合物 晶体结构 分子间弱相互作用 |
| 文章编号： | 1007-4260(2001)02-0023-03 |
The weak interactions occurring between inter-molecule of bis(maleonitriledithiolato)transition metal copmlexes |
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| REN Xiao-ming. The weak interactions occurring between inter-molecule of bis(maleonitriledithiolato)transition metal copmlexes[J]. Journal of Anqing Teachers College(Natural Science Edition), 2001, 7(2): 23-25,34 |
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| Authors: | REN Xiao-ming |
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| Abstract: | Two ion-pair complexes,A[M(mnt) 2](A=1-(4-nitrobezyl)quinolinium or 1-(4-nitrobezyl)pyridinium;M=Ni(Ⅲ) or Fe(Ⅲ);mnt 2- =maleonitriledithiolate),have been preparated and characterized by element analysis,infrared wpectra.The crystal structures of the two complexes reveal that the anions and cations for the two complexes form completely segregated stacking columns in solid state,and there exist the intermolecular weak interactions between cations within the cations stacking columns. |
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| Keywords: | Mnt complex crystal structure intermolecular interaction |
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