| 偶氮苯类人工受体中间体的合成及~1H NMR谱 |
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| 引用本文： | 赵小菁,田甜,支云,范圣第.偶氮苯类人工受体中间体的合成及~1H NMR谱[J].大连民族学院学报,2011,13(5):444-449. |
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| 作者姓名： | 赵小菁 田甜 支云 范圣第 |
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| 作者单位： | 大连民族学院生命科学学院,辽宁大连,116605 |
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| 基金项目： | 基金项目:国家自然科学基金资助项目(20872013):中央高校基本科研业务费专项资金资助项目 |
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| 摘 要： | 在一种仿G蛋白耦合型信号转导的人工超分子系统中引入一类偶氮苯结构的化合物,用来模拟跨膜受体。以苯胺为原料,合成几种人工受体中间体-偶氮苯化合物,选取其中4,4’-二羧基偶氮苯与谷氨酸甲酯(GluOMe)进行连接,得到一种氨基酸甲酯偶氮苯衍生物(Azo-AAOMe),并对其1H NMR谱进行了研究。核磁谱图显示,所合成的化合物正是预期产物。
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| 关 键 词： | 偶氮苯 人工受体 1HNMR谱 |
Synthesis and 1H NMR Property of Azo - benzene Artificial Receptor Intermediate |
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| ZHAO Xiao-jing,TIAN Tian,ZHI Yun,FAN Sheng-di.Synthesis and 1H NMR Property of Azo - benzene Artificial Receptor Intermediate[J].Journal of Dalian Nationalities University,2011,13(5):444-449. |
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| Authors: | ZHAO Xiao-jing TIAN Tian ZHI Yun FAN Sheng-di |
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| Institution: | ZHAO Xiao-jing,TIAN Tian,ZHI Yun,FAN Sheng-di(College of Life Science,Dalian Nationalities University,Dalian Liaoning 116605,China) |
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| Abstract: | A series of Azo - compounds has been introduced into a G - pro Bio - inspired artificial signal transduetion system, to simulating the transmembrane receptor of this system. The photoinduced isomerization of azobenzene between the extended （trans） and compact （cis） conformations has been reversibly triggered by light of two differing wavelengths. Using aniline as the material, a series of azo - benzene artificial receptor intermediate has been prepared. The 4, 4＇ -dicarboxylazobenzene has been combinded with GluOMe, then a amino acid ester azoben- zene derivatives has been synthesized. The 1 H NMR properties of these products have been studied. The results showed that the products are the right compounds. |
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| Keywords: | Azo - benzene artificial receptor 1 H NMR property |
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