| [Ag(C_3H_(10)N_2)]·(C_7H_4NO_4)·2H_2O的合成和结构 |
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| 引用本文： | 仇晓阳,孙林,马继龙,杨松,邵思常.[Ag(C_3H_(10)N_2)]·(C_7H_4NO_4)·2H_2O的合成和结构[J].阜阳师范学院学报(自然科学版),2004,21(1):24-26. |
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| 作者姓名： | 仇晓阳 孙林 马继龙 杨松 邵思常 |
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| 作者单位： | 阜阳师范学院化学系,安徽,阜阳,236041 |
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| 基金项目： | 安徽省自然科学基金资助(2004kj302) |
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| 摘 要： | 以氧化银、4 -硝基苯甲酸和 1,2二氨基丙烷为原料 ,合成出标题配合物 Ag(C3 H10 N2 ) ]·(C7H4NO4)·2H2 O .该配合物经X射线单晶结构分析结果表明 ,属三斜晶系 ,空间群为P-1,a =7.139(2 ) ,b =7.5 0 9(2 ) ,c =14 4 .0 0 7(4 ) ,α=78.5 0 5 (5 ) ,β =78.789(4 ) ,γ =82 .0 2 3(2 )° ,V =717.8(4 ) 3 ,Z =2 ,F(0 0 0 ) =388,Dc =1.5 4 4g/cm3 ,最终偏差因子RI>2 ((I) ]a:R1=0 .0 36 1,wR2 =0 .0 916 .
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| 关 键 词： | 氧化银 配合物 晶体结构 氢键 |
| 文章编号： | 1004-4329(2004)01-0024-03 |
| 修稿时间： | 2003年12月3日 |
Synthesis and Crystal Structure of [Ag(C3H10N2)]·(C7H4NO4)·2H2O] |
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| Qiu Xiao-yang,Sun Lin,Ma Ji-long,Yang Song,Shao Si-chang.Synthesis and Crystal Structure of [Ag(C3H10N2)]·(C7H4NO4)·2H2O][J].Journal of Fuyang Teachers College:Natural Science,2004,21(1):24-26. |
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| Authors: | Qiu Xiao-yang Sun Lin Ma Ji-long Yang Song Shao Si-chang |
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| Abstract: | The colourless crystal of C 10H 18AgN 3O 6 was synthesized and its structure was determined by single crystal X-ray diffraction method. The complex is triclinic, space group P-1, a=7.139(2),b=7.509(2),c=144.007(4)?,α= 78.505(5), β= 78.789(4),γ= 82.023(2)°,V=717.8 (4)?3,Z=2, F(000)=388,Dc=1.544g/cm3, final R$$$$ Qiu Xiao-yang , Sun Lin , Ma Ji-long , Yang Song , Shao Si-chang (Dept. of Chemistry, Fuyang Teachers College, Fuyang, Anhui 236041) Abstract:The colourless crystal of C 10H 18AgN 3O 6 was synthesized and its structure was determined by single crystal X-ray diffraction method. The complex is triclinic, space group P-1, a=7.139(2),b=7.509(2),c=144.007(4)?,α= 78.505(5), β= 78.789(4),γ= 82.023(2)°,V=717.8 (4)?3,Z=2, F(000)=388,Dc=1.544g/cm3, final Ra:R 1=0.0361,wR 2=0.0916. |
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| Keywords: | silver complex crystal structure hydrogen bonds |
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