| 双N－氧化吡啶－2－甲醛缩丙二胺合锌配合物的合成、晶体结构和分子结构 |
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| 引用本文： | 崔爱莉,王凤山,于英.双N－氧化吡啶－2－甲醛缩丙二胺合锌配合物的合成、晶体结构和分子结构[J].吉林大学学报(理学版),1994(2). |
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| 作者姓名： | 崔爱莉 王凤山 于英 |
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| 作者单位： | 吉林大学化学系，长春市成人文理学院 |
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| 摘 要： | 本文报道了双Ｎ－氧化吡啶－２－甲醛缩丙二胺合锌配合物的合成、晶体结构和分子结沟．化合物晶体为正交晶系，空间群Ｐ＿ｎａｍ；晶胞参数ａ＝０．７１４５（８）ｎｍ，ｂ＝１．３７１６（７）ｎｍ，ｃ＝２．２５２７（６）ｎｍ，Ｚ＝４．结构参数经块矩阵最小二乘法精修后，最终一致性因子Ｒ＝０．０７８，Ｒ＿Ｗ＝０．０７１．采用ＥＨＭＯ方法分析了配合物的电子结构和分子轨道，阐明了红外光谱中Ｃ＝Ｎ扣Ｎ一Ｏ振动峰的移动和配合物的成键特性．
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| 关 键 词： | 锌，N－氧化吡啶－2－甲醛，晶体结构 |
Studies on Synthesis,Crystal and Molecule Structures of Zinc Complex with Bis-Schiff Base from Pyridine-2-Aldehyde N-Oxide and Trimethylene |
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| Cui Aili,Wang Fengshan.Studies on Synthesis,Crystal and Molecule Structures of Zinc Complex with Bis-Schiff Base from Pyridine-2-Aldehyde N-Oxide and Trimethylene[J].Journal of Jilin University: Sci Ed,1994(2). |
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| Authors: | Cui Aili Wang Fengshan |
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| Abstract: | The present paper cover;the svnthesis, crvstal and molecule structures of zinccomplex with bis-Schiff base from pyridine-2-aldehyde. The crystal of the complex belongsto orthorhombic system with space group P_nam;parameters of the unit cell are a=0.7145(8)nm,b=1.3716(7) nm,c=2.2527(6)nm: Z=4.The diffraction data were collected with anicolet XRD R_3 fourcircle diffractometer. The structure parameters were refined by the pro-gram of block matrix leatqt square. The final value of R was 0.078. The electronic structureof the coordination compound was analysed hy the EHMO method. |
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| Keywords: | zinc pyridine-2-aldehyde-N-oxide crystal structure |
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