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葡萄糖改性有机硼交联剂在水基聚乙烯醇压裂液中的应用
引用本文:隋明炜,沈一丁,李宪文,钟新荣,薛小佳,丁里.葡萄糖改性有机硼交联剂在水基聚乙烯醇压裂液中的应用[J].西安石油大学学报(自然科学版),2011,26(2):89-92,122.
作者姓名:隋明炜  沈一丁  李宪文  钟新荣  薛小佳  丁里
作者单位:1. 陕西科技大学轻化工助剂化学与技术教育部重点实验室,陕西,西安,710021
2. 中国石油长庆油田油气工艺技术研究院,陕西西安,710021
3. 川庆钻探公司长庆井下技术作业公司,陕西,西安,710021
基金项目:国家重大专项示范工程子课题
摘    要:为验证聚乙烯醇作为水基冻胶压裂液的可行性,提出葡萄糖改性有机硼交联剂的压裂液体系.采用实验室自制葡萄糖改性有机硼交联剂,得出原料最佳配比n(硼砂):n(葡萄糖)=1∶1.5.葡萄糖改性有机硼交联剂对聚乙烯醇有很好的延时性和耐高温性,其交联时间可以控制在60~500 s之间,耐热温度在70℃左右.以聚乙烯醇为稠化剂的水基冻胶压裂液的最低有效浓度可达1.1%.

关 键 词:水基压裂液  交联剂  有机硼  葡萄糖  聚乙烯醇  交联延迟

Application of organic boron cross-linker modified by glucose in polymer alcohol
SUI Ming-wei,SHEN Yi-ding,LI Xian-wen,ZHONG Xin-rong,XUE Xiao-jia,DING Ling.Application of organic boron cross-linker modified by glucose in polymer alcohol[J].Journal of Xian Shiyou University,2011,26(2):89-92,122.
Authors:SUI Ming-wei  SHEN Yi-ding  LI Xian-wen  ZHONG Xin-rong  XUE Xiao-jia  DING Ling
Institution:SUI Ming-wei1,SHEN Yi-ding1,LI Xian-wen2,ZHONG Xin-rong3,XUE Xiao-jia2,DING Ling2(1.Key Laboratory of Education Ministry for Aids Chemistry &Technology for Light Chemical Industry,Shaanxi University of Science & technology,Xi'an 710021,Shaanxi,China,2.Research Institute of Oil and Gas Technology,Changqing Oilfield Company,3.Changqing Downhole Operation Company,Chuanqing Drilling Company,China)
Abstract:In order to verify the feasibility of polymer alcohol as the thickener of water-based fracturing fluid,a water-based fracturing fluid system is proposed,in which polymer alcohol is used as the thickener,the organic boron modified by glucose is used as cross-linker.The organic boron cross-linker is prepared in laboratory,and the optimal raw material ratio n(borax):n(glucose)is 1∶1.5.The modified organic boron cross-linker has a good cross-linking delaying effect to polymer alcohol.It can control cross-linking time in 60~500 s,and its thermo-tolerant temperature is about 70 ℃.The minimum effective mass fraction of polymer alcohol in water-based fracturing fluid reaches to 1.1%,which can reduce the use of the cost of fracturing measures.
Keywords:water-base fracturing liquid  cross-linker  organic boron  glucose  polvingyl alcohol  crosslinking delaying  
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