| 柠檬酸柱撑水滑石的制备及结构表征 |
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| 引用本文： | 王剑峰,张亚非,郭宪吉. 柠檬酸柱撑水滑石的制备及结构表征[J]. 四川理工学院学报(自然科学版), 2009, 22(1) |
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| 作者姓名： | 王剑峰 张亚非 郭宪吉 |
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| 作者单位： | 郑州大学化工学院,郑州,450001;郑州大学化学系,郑州,450001 |
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| 摘 要： | 首先采用一定方法合成了水滑石锌铝碳酸根双氢氧化物(Zn2A l-CO3-LDHs)及镁铝碳酸根双氢氧化物(Mg2A l-CO3-LDHs),并通过用粉末X射线衍射(XRD)、红外光谱(IR)等手段对产物的结构进行了表征。接着以水滑石锌铝碳酸根双氢氧化物(Zn2A l-CO3-LDHs)及镁铝碳酸根双氢氧化物(Mg2A l-CO3-LDHs)为前体,以乙二醇为介质,用离子交换法制备了柠檬酸柱撑层状双氢氧化物(Zn2A l-C6H7O7-LDHs和Mg2A l-C6H7O7-LDHs),并用粉末X射线衍射(XRD)、红外光谱(IR)等测试技术对样品进行了表征。结果表明,C6H7O7-可以完全取代水滑石层间的CO32-柱撑水滑石具有良好的层状结构。
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| 关 键 词： | 水滑石 柱撑水滑石 柠檬酸 制备 结构表征 |
Preparation and Structrural Characterization of Citric Acid-pillared Hydrotalcites |
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| WANG Jian-feng,ZHANG Ya-fei,GUO Xian-ji. Preparation and Structrural Characterization of Citric Acid-pillared Hydrotalcites[J]. Journal of Sichuan University of Science & Engineering(Natural Science Editton), 2009, 22(1) |
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| Authors: | WANG Jian-feng ZHANG Ya-fei GUO Xian-ji |
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| Affiliation: | 1.College of Chemical Engineering;Zhengzhou University;Zhengzhou 450001;China;2.Department of Chemistry;China |
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| Abstract: | The Zn-Al and Mg-Al layered double hydroxides(denoted as Zn2Al-CO3-LDHs and Mg2Al-CO3-LDHs) were prepared by coprecipitation method.The structures of the products were characterized by XRD,IR methods.Zn2Al-CO3-LDHs and Mg2Al-CO3-LDHs as precursors,for the medium of ethylene glycol,prepared by ion exchange Zn2Al-C6H7O7-LDHs and Mg2Al-C6H7O7-LDHs.The structures of the products were characterized by XRD,IR methods.The results show that: C6H7O7-can replace hydrotalcite layer of CO32-,pillared hydrotalcite has g... |
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| Keywords: | hydrotalcite pillared hydrotalcite citric acid preparation structural characterization |
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