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Sm(Ⅲ)配合物发光特征的荧光光谱和光声光谱的研究
引用本文:雍克岚,吕敬慈,苏庆德.Sm(Ⅲ)配合物发光特征的荧光光谱和光声光谱的研究[J].上海大学学报(自然科学版),2000,6(3):243-247.
作者姓名:雍克岚  吕敬慈  苏庆德
作者单位:1. 上海大学,生命科学学院,上海,201800
2. 上海大学,理学院,上海,201800
3. 中国科学技术大学,化学系,合肥,230026
摘    要:作者运用荧光光谱和光声光谱技术,研究了固体Sm(DBM)3和Sm(SAL)3配合的发光特性,能量传递过程和能级状况,并对配合和中心离子间不同的能量传递途径及能量传递的有效性进行了讨论。

关 键 词:钐配合物  荧光光谱  光声光谱  能量传递  发光特性

Study of the Luminescence Properties of Sm3+ Complexes by Fluorescence and Photoacoustic Spectroscopy
YONG Ke lan ,LU Jing ci ,SU Qing de.Study of the Luminescence Properties of Sm3+ Complexes by Fluorescence and Photoacoustic Spectroscopy[J].Journal of Shanghai University(Natural Science),2000,6(3):243-247.
Authors:YONG Ke lan  LU Jing ci  SU Qing de
Institution:YONG Ke lan 1,LU Jing ci 2,SU Qing de 3
Abstract:The luminescence properties, energy transfer processes and energy levels of solid state Sm 3 complexes with salicylic acid (SAL) and dibenzoylmethide (DBM) are studied by fluorescence and photoacoustic spectroscopy at room temperature. The different energy transfer paths and the efficiency of intramolecular energy transfer between the ligands and the central ion are discussed according to Dexter's theory.
Keywords:samarium complex  dibenzoylmethide  salicylic acid  fluorescence spectroscopy  photoacoustic spectroscopy  energy transfer
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