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金属离子对钢在没食子酸/硫酸介质中的腐蚀行为研究
引用本文:白玮,李向红,屈庆,江书安,彭光春.金属离子对钢在没食子酸/硫酸介质中的腐蚀行为研究[J].云南大学学报(自然科学版),2007,29(5):507-510.
作者姓名:白玮  李向红  屈庆  江书安  彭光春
作者单位:1. 云南民族大学,化学与生物技术学院,云南,昆明,650031
2. 西南林学院,基础部,云南,昆明,650224
3. 云南大学,化学系,云南,昆明,650091
基金项目:国家自然科学基金,云南省教育厅资助项目
摘    要: 用失重法研究了4种金属离子(Na+,Zn2+,Cu2+,Fe3+)在0.5 mol/L H2SO4以及500 mg/L没食子酸+0.5 mol/L H2SO4介质中在20℃对冷轧钢腐蚀行为的影响.结果表明:Cu2+对钢的腐蚀起抑制作用;而其余3种金属离子(Na+,Zn2+,Fe3+)对钢的腐蚀起加速作用.在相同条件下,冷轧钢在0.5 mol/L H2SO4溶液中的腐蚀速率顺序为:Cu2+2++3+;而在500 mg/L没食子酸+0.5 mol/L H2SO4介质中,腐蚀速率顺序为:Cu2+2+3++.

关 键 词:  没食子酸  金属离子  腐蚀
文章编号:0258-7971(2007)05-0507-04
修稿时间:2007-01-11

Effect of metallic cations on the corrosion behavior of cold rolled teel in H2SO4/gallic acid media
BAI Wei,LI Xiang-hong,QU Qing,JIANG Shu-an,PENG Guang-chun.Effect of metallic cations on the corrosion behavior of cold rolled teel in H2SO4/gallic acid media[J].Journal of Yunnan University(Natural Sciences),2007,29(5):507-510.
Authors:BAI Wei  LI Xiang-hong  QU Qing  JIANG Shu-an  PENG Guang-chun
Institution:1. School of Chemistry and Bio-Science, Yunnan Nationalities University, Kunming 650031, China; 2. Department of Fundamental Courses, Southwest Forestry University, Kunming 650224, China; 3. Department of Chemistry, Yunnan University, Kunming 650091, China
Abstract:The corrosion behavior effect of metallic cations(Na+,Zn2+,Cu2+,Fe3+) in H2SO4 /gallic acid solution at 20 ℃ on the cold rolled steel was studied by weight loss method.The results showed that Cu2+ inhibit the corrosion of cold rolled steel,whereas the other metallic cations accelerate the steel corrosion.In 0.5 mol/L H2SO4 solution,the corrosion rate of cold rolled steel follows the order:Cu2+2+3++.In 500 mg/L gallic acid+0.5 mol/L H2SO4 solution,the corrosion rate of cold rolled steel follows the order:Cu2+2++3+.The corrosion behavior was also discussed.
Keywords:steel  gallic acid  metallic cations  corrosion
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