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盐粒沉降对Zn大气腐蚀的影响
引用本文:王凤平,陈华,李晓刚.盐粒沉降对Zn大气腐蚀的影响[J].北京科技大学学报,2002,24(4):445-448.
作者姓名:王凤平  陈华  李晓刚
作者单位:1. 北京科技大学材料科学与工程学院,腐蚀与防护中心,北京,100083;2. 北京科技大学材料科学与工程学院,腐蚀与防护中心,北京,100083;金属腐蚀与防护国家重点试验室,沈阳,110016
基金项目:国家自然科学基金;50171011;
摘    要:使用石英晶体微天平(QCM)并结合红外透射光谱(IRTS)研究了海洋大气环境和工业大气环境对金属Zn在薄液膜下大气腐蚀的影响.QCM试验表明:研究的几种电解质中,NaCl对Zn的腐蚀最严重,其次是(NH4)2SO4,NaNO3较弱,Na2CO3最轻微.结合红外光谱对腐蚀产物的分析,阐述了各种不同电解质条件下的腐蚀机理.

关 键 词:大气腐蚀    电解质  薄液膜  石英晶体微天平
修稿时间:2000年2月12日

Effect of Deposition of Electrolytes on Atmospheric Corrosion of Zn under Thin Liquid Film
WANG Fengping,CHEN Hua,LI Xiaogang Material Science and Engineering School,UST Beijing,China State Key Laboratory of Corrosion and Protection of Metals.Shenyang ,China.Effect of Deposition of Electrolytes on Atmospheric Corrosion of Zn under Thin Liquid Film[J].Journal of University of Science and Technology Beijing,2002,24(4):445-448.
Authors:WANG Fengping  CHEN Hua  LI Xiaogang Material Science and Engineering School  UST Beijing    China State Key Laboratory of Corrosion and Protection of MetalsShenyang  China
Institution:WANG Fengping,CHEN Hua,LI Xiaogang1) Material Science and Engineering School,UST Beijing,100083,China2) State Key Laboratory of Corrosion and Protection of Metals.Shenyang 110016,China
Abstract:Effect of sea atmospheric environment and industrial atmospheric on corrosion of metal Zn has been studied for the first time using Quartz Crystal Microbalance(QCM) combined with Infrared Transmissive Spectroscopy(IRTS). QCM results have shown that NaCl deposited on surface of zinc is the most corrosive electrolyte among selected electrolytes to atmospheric corrosion of zinc, (NH4)2SO4 deposited on the surface of zinc is the second, NaNO3 weak, and Na2CO3 the slightest. Combined with the IRTS analysis of the corrosion products, the corrosion mechanism of Zn under thin liquid film has elaborated.
Keywords:atmospheric corrosion  zinc  electrolyte  thin liquid film  quartz crystal microbalance
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