| 高自旋镍(Ⅲ)配合物的合成与表征 |
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| 引用本文： | 展树中,马登勇.高自旋镍(Ⅲ)配合物的合成与表征[J].河南师范大学学报(自然科学版),1992(3). |
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| 作者姓名： | 展树中 马登勇 |
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| 作者单位： | 河南师范大学化学系
(展树中)，大连理工大学化学系(马登勇) |
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| 摘 要： | 我们利用铁氰化钾兼做氧化剂和沉淀剂,用以氧化NiLn]~(2+)(L为en、pn和dien,分别表示乙二胺、1.2-丙二胺和二乙三胺)得到比较稳定的3种溶解度较小的暗绿色晶体。经元素分析、穆斯堡尔谱(Mossbauer)、紫外光谱、磁化率、摩尔电导和顺磁共振光谱(ESR)的测定,证明它们是高自旋Ni(Ⅲ)配合物。
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| 关 键 词： | 配合物 高自旋 光谱 三价镍 |
PREPARATION AND PROPERTIES OF TRIVALENT NICKEL COMPLEXES |
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| Zhan Shuzhong,Ma Dengyong.PREPARATION AND PROPERTIES OF TRIVALENT NICKEL COMPLEXES[J].Journal of Henan Normal University(Natural Science),1992(3). |
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| Authors: | Zhan Shuzhong Ma Dengyong |
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| Institution: | Zhan Shuzhong,Ma Dengyong Department of Chenmisity Depart. of chemisty,Dalian University of Science and Technology |
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| Abstract: | The number of known nikel(Ⅲ) compounds is small. Most of them are in low-spin(oneimpaired electron). In this article we report the preparation, isolation and charateritation of nicked(Ⅲ)complexes with ethylenediamine, 1.2-propaedimine. clithylenediamine, the nickel(Ⅲ) oxidation statewhich is in high-spin configuration. The nature of nickel(Ⅲ) complexes are studied by using ESR,UV-visible spectroscopy, Mossbauer and magnetic monent measurements. Various criteria are employedto estabilish the oxidation state of nickel(Ⅲ). |
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| Keywords: | complex high-spin spectra trivalent nickel |
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