| 分子印迹聚合物及其在有机合成中的应用 |
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| 引用本文： | 袁小亚,余响林,黄锦霞. 分子印迹聚合物及其在有机合成中的应用[J]. 湖北大学学报(自然科学版), 2002, 24(3): 250-255 |
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| 作者姓名： | 袁小亚 余响林 黄锦霞 |
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| 作者单位： | 湖北大学,高分子材料湖北省重点实验室,湖北,武汉,430062;湖北大学,高分子材料湖北省重点实验室,湖北,武汉,430062;湖北大学,高分子材料湖北省重点实验室,湖北,武汉,430062 |
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| 基金项目： | 国家自然科学基金(29872012) |
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| 摘 要： | 分子印迹技术是近年发展起来的一种新颖的有机合成手段。评述了分子印迹聚合物的制备方法及尚有待深入的关键问题,重点介绍了分子印迹聚合物用作催化剂在有机合成中应用的优势及研究近况,特别是用作手性催化剂不对称合成光学活性物质。并设计将分子印迹聚合物用于催化醛酮不对称还原反应,可获得较高光学产率的手性醇,其％e.e值达95％以上。
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| 关 键 词： | 分子印迹聚合物 催化剂 手性 不对称有机合成 |
| 文章编号： | 1000-2375(2002)03-0250-06 |
| 修稿时间： | 2001-10-26 |
Molecularly imprinted polymer and its application in organic synthesis |
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| Yuan Xiaoya,Yu Xianglin,Huang Jinxia. Molecularly imprinted polymer and its application in organic synthesis[J]. Journal of Hubei University(Natural Science Edition), 2002, 24(3): 250-255 |
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| Authors: | Yuan Xiaoya Yu Xianglin Huang Jinxia |
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| Abstract: | Molecular imprinting is a novelly organic synthetic technology developed in recent yeas.This review describes the preparation of molecularly imprinted polymer(MIP) and the critical problems to be fiirthur explored, and emphasises on the introduction of MIP's superiority of its application in the field of organic synthesis as a catalyst and the present research, especially about its use as the chiral catalyst during the synthesis of optically - activated reagents . MIP is designed to asymmetrically catalysize the reducing - reaction of the aldehydes or ketones and the higher optical yields of chiral alcohols can be obtained with the value of % e. e over 95 % . |
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| Keywords: | molecularly imprinted polymer catalyst chirality asymmetry organic synthesis |
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