| 碳原子数估算有机物的热力学函数 |
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| 引用本文： | 李大成,周立国,孟庆华.碳原子数估算有机物的热力学函数[J].聊城大学学报(自然科学版),1994(4). |
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| 作者姓名： | 李大成 周立国 孟庆华 |
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| 摘 要： | 以文献报道的部分正烷烃、正烯烃、正炔烃、正烷基苯、正烷硫醇２９８Ｋ下气态化合物标准生成焓、标准生成自由能、标准熵的数据为基础，通过计算机进行回归分析，得到了这些有机物的标准生成焓，标准生成自由能，标准熵均与碳原子数（ｎ）呈良好的线性关系．即据这些关系式分别计算了一系列直链有机物的，其结果与文献值相吻合．
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| 关 键 词： | 热力学函数，碳原子数，回归分析 |
ESTIMATION OF THE FUNATION OF THERMODYNAMICS OF ORGANIC COMPOUND FROM ATOMIC NUMBER OF CARBON |
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| Li Da Cheng,Zhou Li Guo,Meng Qing Hua.ESTIMATION OF THE FUNATION OF THERMODYNAMICS OF ORGANIC COMPOUND FROM ATOMIC NUMBER OF CARBON[J].Journal of Liaocheng University:Natural Science Edition,1994(4). |
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| Authors: | Li Da Cheng Zhou Li Guo Meng Qing Hua |
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| Institution: | Department of Chemistry |
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| Abstract: | The experiential aquations relating function of thermodynamics of,normal aldane,normal alkene,normal alkyne,normal thiol and noimal alkyl benzene to atomic number of carbon were given by regerssion analysis on microcomputer The results can be expressed to.The calculation results of function of thermodynamics by these formulations are relatively close to the valuse valuse of literaure. |
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| Keywords: | Function of themodynamics Atomic number of carbon Regression analysis |
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