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弱碱与微量强碱混合液的测定
引用本文:贺萍,王朝霞.弱碱与微量强碱混合液的测定[J].烟台大学学报(自然科学与工程版),1995(3):77-79.
作者姓名:贺萍  王朝霞
作者单位:烟台大学,烟台市卫生防疫站
摘    要:提出了强酸滴定弱碱与微量强碱共存的滴定通式,并提出用最小二乘法处理电位滴定数据,求算弱碱与微量强碱的浓度,结果令人满意,文中还解释了强碱的“空白”值是由于未进行活度校正引起的,而且经活度系数校正以后可获得更为准确的结果。

关 键 词:酸碱滴定  最小二乘法  离子活度  弱碱  强碱  测定

Determination of a Weak Base and Trace of a Strong Base in a Solution
He Ping,Liu Wanhui,Wang Zhaoxia.Determination of a Weak Base and Trace of a Strong Base in a Solution[J].Journal of Yantai University(Natural Science and Engineering edirion),1995(3):77-79.
Authors:He Ping  Liu Wanhui  Wang Zhaoxia
Institution:He Ping;Liu Wanhui;Wang Zhaoxia(Yantai University)(Yantai sanitation and Antiepidemic Station )
Abstract:This paper presen ts a gercral equation of a strong acid to titrate a solution containing a weak base and trace of a strong base,The least square methed was used for calculating the concentrations of the two bases.The " blank yalue" of strong base appeared because the ion activity coefficient was not calibrated.Thus the more accurate results can be obtained after calibration of the ion activity coefficient.
Keywords:Acid-base titration  Least square methed  Ion activity  
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