| 稀土元素与邻氨基苯酚和4-(3,5-二苯基-2-吡唑啉-1-)苯磺酸的三元配合物的合成与研究 |
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| 引用本文： | 唐定兴,王博.稀土元素与邻氨基苯酚和4-(3,5-二苯基-2-吡唑啉-1-)苯磺酸的三元配合物的合成与研究[J].安徽师范大学学报(自然科学版),1997(1). |
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| 作者姓名： | 唐定兴 王博 |
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| 作者单位： | 安徽机电学院食品系(唐定兴)，兰州化学物理研究所(王博) |
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| 摘 要： | 制备了分子式为［Ｌｎ（ＯＡＰ）２（Ｄｐｂｓ）２］Ｄｐｂｓ（ＯＡＰ：邻氨基苯酚．Ｄｐｂｓ－１：４－（３，５，－二苯基－２－吡唑啉－１－）苯磺酸根阴离子）的三元配合物，产物通过元素分析、电导、热重、红外光谱、紫外光谱及１Ｈ核磁共振谱进行了研究，结果表明ＯＡＰ为中性二齿配体而Ｄｐｂｓ为负的单齿配体，结构为八面体型
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| 关 键 词： | 稀土元素 三元配合物 邻氨基苯酚 4－（3，5－二苯基－2－吡唑啉－1－）苯磺酸 |
SYNTHESIS AND STUDIES OF TERNARY COMPLEXES OF RARE EARTH ELEMENTS WITH O AMINOPHENOL AND 4 (3,5 DIPHENYL 2 PYRAZOLIN 1 YL) BENZENESULPHONATE ION |
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| Tang Dingxing.SYNTHESIS AND STUDIES OF TERNARY COMPLEXES OF RARE EARTH ELEMENTS WITH O AMINOPHENOL AND 4 (3,5 DIPHENYL 2 PYRAZOLIN 1 YL) BENZENESULPHONATE ION[J].Journal of Anhui Normal University(Natural Science Edition),1997(1). |
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| Authors: | Tang Dingxing |
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| Abstract: | Ternary Complexes of the general formula Ln(OAP) 2(Dpbs) 2]Dpbs have been prepared. The complexex were characterized by elemental analyses, conductivity measurements, Thermal methods, IR, UV, and 1 Hnmr Spectral studies. The results show that OAP behaves as a neutral bibentate and Dpbs a negative unidentate ligand. |
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| Keywords: | rare earth elements\ ternary complex\ O aminophenol\ 4 (3 5 diphenyl 2 pyrazolin 1 yl) benzenesulphonic acid |
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