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电导法测定表面活性剂稀溶液的活度系数
引用本文:任丽慧,傅式洲,魏西莲.电导法测定表面活性剂稀溶液的活度系数[J].聊城师院学报,2009(4):41-44.
作者姓名:任丽慧  傅式洲  魏西莲
作者单位:聊城大学化学化工学院,山东聊城252059
基金项目:山东省自然科学基金资助项目(Y2006B05);聊城大学科研发展基金及化学化工学院教学研究项目资助项目
摘    要:用电导法测定了293K下十二烷基磺酸钠水溶液的活度系数.根据Kohlraush经验公式外推得到极限摩尔电导,经Debye—Hucker和Osager—Falkenhangen公式计算出293K下十二烷基磺酸钠的平均活度系数.结果表明:在表面活性剂小于CMC的范围内其溶液的平均活度系数几乎不变.

关 键 词:电导法  十二烷基磺酸钠  活度系数

Determination of Conductivity of Surfactant Activity Coefficients of Dilute Aqueous Solutions
REN Li-hui,FU Shi-zhou,WEI Xi-lian.Determination of Conductivity of Surfactant Activity Coefficients of Dilute Aqueous Solutions[J].Journal of Liaocheng Teachers University(Natural Science Edition),2009(4):41-44.
Authors:REN Li-hui  FU Shi-zhou  WEI Xi-lian
Institution:(School of Chemistry and Chemical Engineering, Liaocheng Univercity, Liaocheng 252059, China)
Abstract:Introduction of electricity determined by sodium dodecyl sulfate on 293K of activity coefficients in aqueous solution. According to Kohlraush empirical formula has been extrapolated molar conductivity limit, the Debye-Hucker and Osager-Falkenhangen formula to calculate sodium dodecyl sulfate on 293K the average activity coefficient. The results showed that the CMC of surfaetant is less than its solution within the scope of the average activity coefficient is almost unchanged.
Keywords:conductivity  sodium dodecyl sulfate  activity coefficient
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