| Keggin 型硼钨酸与1,4-二(1H-吡唑甲基)苯及铜有机-无机杂化物的二维网状结构与性质 |
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| 引用本文： | 侯广峰,毕立华,李豹,王斌,吴立新.Keggin 型硼钨酸与1,4-二(1H-吡唑甲基)苯及铜有机-无机杂化物的二维网状结构与性质[J].科学通报,2011,56(9):635-639. |
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| 作者姓名： | 侯广峰 毕立华 李豹 王斌 吴立新 |
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| 作者单位： | 超分子结构与材料国家重点实验室吉林大学化学学院; |
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| 基金项目： | 国家重点基础研究发展计划(2007CB808003); 国家自然科学基金(20973082,20921003,20703019,21073076)资助项目 |
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| 摘 要： | 在水热条件下, 以Keggin 型硼钨酸盐和1,4-二(1H-吡唑甲基)苯作为配体与硝酸 铜反应, 制备了一个新的有机-无机杂化化合物 Cu4L5(HL)]BW12O40] {L = 1,4-二(1H- 吡唑甲基)苯}. 单晶X 射线衍射分析表明, 此化合物具有新颖的由十核铜环单元共边 相互连接而构成的波浪形二维网状结构. 此外, 循环伏安测试结果显示, 其还原过程 是由表面控制和扩散控制共同完成的.
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| 关 键 词： | 有机-无机杂化化合物 硼钨酸盐 晶体结构 循环伏安 |
| 收稿时间： | 2010-10-25 |
Organic-inorganic hybrid compound of Keggin-type borotungstate, 1,4-bis((1H-pyrazol-1-yl)methyl)benzene and copper: 2D network structure and properties |
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| HOU GuanFeng,BI LiHua,LI Bao,WANG Bin & WU LiXin State Key Laboratory of Supramolecular Structure , Materials,College of Chemistry,Jilin University,Changchun ,China.Organic-inorganic hybrid compound of Keggin-type borotungstate, 1,4-bis((1H-pyrazol-1-yl)methyl)benzene and copper: 2D network structure and properties[J].Chinese Science Bulletin,2011,56(9):635-639. |
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| Authors: | HOU GuanFeng BI LiHua LI Bao WANG Bin & WU LiXin State Key Laboratory of Supramolecular Structure Materials College of Chemistry Jilin University Changchun China |
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| Institution: | HOU GuanFeng,BI LiHua,LI Bao,WANG Bin & WU LiXin State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012,China |
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| Abstract: | An organic-inorganic hybrid compound Cu4L5(HL)]BW12O40] {L=1,4-bis((1H-pyrazol-1-yl)methyl)benzene} was produced by hydrothermally synthesis from Keggin-type borotungstate, L, and Cu(NO3)2. The hybrid compound displayed a novel wavelike 2D network formed by shared edges of a core unit composed of ten Cu in a cyclic arrangement. Cyclic voltammetry showed that the reduction process was surface and diffusion controlled. |
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| Keywords: | organic-inorganic hybrid compound borotungstate crystal structure cyclic voltammetry |
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