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臭氧对煤粉燃烧的影响
引用本文:张曦东,张建良,郭豪,龚必侠.臭氧对煤粉燃烧的影响[J].北京科技大学学报,2009,31(3).
作者姓名:张曦东  张建良  郭豪  龚必侠
作者单位:北京科技大学冶金与生态工程学院,北京,100083
基金项目:国家“十一五”科技支撑计划资助项目(No.2006BAE03A01)
摘    要:根据强紫外线辐射空气可产生臭氧的原理,将经紫外辐射后的空气通入热天平与煤粉发生燃烧反应,采用热分析方法研究臭氧对煤粉燃烧的影响.实验表明紫外辐射空气得到的少量臭氧使煤粉燃烧的失重和放热时间提前.对煤粉燃烧的动力学进行分析,结果显示臭氧使煤粉燃烧反应的活化能降低.紫外线激发高温氧气产生氧原子的热力学计算结果表明:温度越高,氧分子越容易被紫外线激发为氧原子.提出了使用强紫外线辐射热风促进高炉喷煤燃烧的设想.

关 键 词:臭氧  紫外辐射  煤粉燃烧  高炉喷煤  

Effect of ozone on coal combustion
ZHANG Xidong,ZHANG Jian-liang,GUO Hao,GONG Bi-xia.Effect of ozone on coal combustion[J].Journal of University of Science and Technology Beijing,2009,31(3).
Authors:ZHANG Xidong  ZHANG Jian-liang  GUO Hao  GONG Bi-xia
Abstract:With the principle that ozone generates when air is exposed to strong UV radiation,UV-radiated air flowed into a thermobalance to react with pulverized coal.The thermal analysis method was used to study the effect of ozone on coal combustion.It is showed that small amount of ozone can advance the burning time and the weightlessness time of pulverized coal.Dynamics analysis reveals that ozone decreases the activation energy of pulverized coal combustion reaction.Thermodynamic calculations show that the highe...
Keywords:ozone  UV radiation  pulverized coal combustion  powder coal injection  
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