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羰基钴催化下卤代烃与硫的反应及其机理研究
引用本文:王进贤.羰基钴催化下卤代烃与硫的反应及其机理研究[J].西北师范大学学报,1994,30(4):96-97.
作者姓名:王进贤
作者单位:西北师范大学化学系
基金项目:甘肃省自然科学基金,甘肃省教委基金
摘    要:羰基钴催化下卤代烃与硫的反应及其机理研究王进贤(化学系)第一作者简介王进贤,男,56岁。1960年毕业于西北师范学院化学系,现为西北师范大学化学系教授,硕士研究生导师。主要研究方向为精细有机合成与金属有机化学,先后在国内外学术刊物发表论文70多篇;中...

关 键 词:羰基钴  相转移催化  卤代烃  

Study on the Reaction and Mechanism for Benzyl Chlorides with Sulfur under Co_2(CO)_8
Wang Jin Xian.Study on the Reaction and Mechanism for Benzyl Chlorides with Sulfur under Co_2(CO)_8[J].Journal of Northwest Normal University Natural Science (Bimonthly),1994,30(4):96-97.
Authors:Wang Jin Xian
Institution:Department of Chemistry
Abstract:The reaction and the mechanism for benzyl chlorides with sulfur under Co_2(CO)_8 is reported. Dibenzylsulfides and dibenzyldisulfides are obtained by the phase transfer catalysed reaction of benzylchioride with sulfur in the presence of catalytic amounts of cobalt earbonyl complexes. The reactionmechanism is briefly discussed.
Keywords:rcaction and mechanism  benzyl chlorides with sulfur  Co_2(CO)_8
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