| 对氟苯甲醛的合成研究 |
| |
| 引用本文： | 刘东宇,刘影,刘军,顾万友.对氟苯甲醛的合成研究[J].中央民族大学学报(自然科学版),2014,23(3):28-32. |
| |
| 作者姓名： | 刘东宇 刘影 刘军 顾万友 |
| |
| 作者单位： | 阜新汉道化工有限责任公司,辽宁阜新,123000 |
| |
| 摘 要： | 本文对氟苯甲醛的合成路线进行了深入研究,得到优化的工艺条件.选定氟化反应温度为210℃,物质的量n（对氯甲苯）∶n（KF）∶n（环丁砜）∶n（催化剂）为1∶1.5∶0.2∶0.05来合成对氟甲苯.对氟甲苯侧链氯化后分离出二三氯化物直接用90％硫酸水解得到对氟苯甲醛.对氟苯甲醛综合收率77％,副产物为对氟苯甲酸.
|
| 关 键 词： | 对氯甲苯 氟化反应 对氟苯甲醛 氯化 水解 |
Study on the Synthetic Route of 4-Fluorobenzaldehyde |
| |
| LIU Dong-yu,LIU Ying,LIU Jun,GU Wan-you.Study on the Synthetic Route of 4-Fluorobenzaldehyde[J].Journal of The Central University for Nationalities(Natural Sciences Edition),2014,23(3):28-32. |
| |
| Authors: | LIU Dong-yu LIU Ying LIU Jun GU Wan-you |
| |
| Institution: | (Fuxin HanDao Chemical Co. , Ltd, Fuxin 123000, China) |
| |
| Abstract: | The process conditions of 4-Fluorobenzaldehyde was as follows： fluorination reaction temperature was 210℃ , 4-chlorotoluene： potassium fluoride： Sulfolane： catalyst = 1 ： 1.5： 0.2：0.05 （the amount of substance）. After the side-chain of 4-Fluorotoluene is chlorinated, dichloride and triehloride was separated and directly hydrolyzed with 90% sulfuric acid. Finally 4- Fluorobenzaldehyde can be obtained. The comprehensive yield of 4-Fluorobenzaldehyde is 77% , the byproduct was 4-fluorobenzoic acid. |
| |
| Keywords: | 4-chlorotoluene fluorination reaction 4-fluorobenzaldehyde chloride hydrolysis |
| 本文献已被 维普 等数据库收录！ |
|
