| 磷钨酸/硅胶催化剂催化合成丁醛1,2-丙二醇缩醛 |
| |
| 引用本文： | 杨水金,孔书益.磷钨酸/硅胶催化剂催化合成丁醛1,2-丙二醇缩醛[J].井冈山大学学报（自然科学版）,2011(4):41-43,52. |
| |
| 作者姓名： | 杨水金 孔书益 |
| |
| 作者单位： | 湖北师范学院化学与环境工程学院; |
| |
| 基金项目： | 湖北省自然科学基金项目(2005ABA053) |
| |
| 摘 要： | 以溶胶-凝胶法自制的磷钨酸/硅胶为催化剂,通过丁醛和1,2-丙二醇为原料反应合成丁醛1,2-丙二醇缩醛,探讨了磷钨酸/硅胶催化剂对缩醛反应的催化活性,用正交试验法较系统地研究了醛醇量比、催化剂用量、带水剂用量、反应时间诸因素对产品收率的影响.实验表明:磷钨酸/硅胶是合成丁醛1,2-丙二醇缩醛的良好催化剂,在n(丁醛):...
|
| 关 键 词： | 丁醛1 2-丙二醇缩醛 磷钨酸/硅胶 催化剂 缩醛反应 |
CATALYTIC SYNTHESIS OF BUTYRALDEHYDE 1,2-PROPANEDIOL ACETAL WITH PHOSPHOTUNGSTIC ACID/SILICA |
| |
| YANG Shui-jin,KONG Shu-yi.CATALYTIC SYNTHESIS OF BUTYRALDEHYDE 1,2-PROPANEDIOL ACETAL WITH PHOSPHOTUNGSTIC ACID/SILICA[J].Journal of Jinggangshan University(Natural Sciences Edition),2011(4):41-43,52. |
| |
| Authors: | YANG Shui-jin KONG Shu-yi |
| |
| Institution: | YANG Shui-jin,KONG Shu-yi(College of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi,Hubei 435002,China) |
| |
| Abstract: | Butyraldehyde 1,2-propanediol acetal was synthesized from butyraldehyde and 1,2-propanediol in the presence of phosphotungstic acid/silica prepared by sol-gel method.The effects of operation parameters such as molar ratio of butyraldehyde to 1,2-propanediol,the dosage of catalyst,the volume of cyclohexane as the water-carrying agent and reaction time on the yield were measured and analyzed in order to optimize these operation conditions.Under the experimental conditions of molar ratio of butyraldehyde to 1,... |
| |
| Keywords: | butyraldehyde 1 2-propanediol acetal phosphotungstic acid/silica catalysis acetalization |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《井冈山大学学报（自然科学版）》浏览原始摘要信息 |
| 点击此处可从《井冈山大学学报（自然科学版）》下载免费的PDF全文 |
|
