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氯丁橡胶和甲基丙烯酸三丁基锡酯自由基接枝共聚的研究
引用本文:钱庆荣,吴元辉.氯丁橡胶和甲基丙烯酸三丁基锡酯自由基接枝共聚的研究[J].福建师范大学学报(自然科学版),1996,12(3):54-58.
作者姓名:钱庆荣  吴元辉
摘    要:研究了甲基丙烯酸三丁基锡酯与氯胶的接枝共聚合反应,测定了单体转化率和接枝率,探讨了共聚合反应的条件,采用红外光谱、核磁共振波谱对共聚物进行了结构和性能的表征,还初步进行了防霉实验。

关 键 词:氯丁橡胶  共聚合反应  接枝共聚  TBTM

Studies of Free Radical Grafting Copolymerization of Neoprene and Tributyltin Methacrylate
Qian Qingrong,Wu Yuanhui.Studies of Free Radical Grafting Copolymerization of Neoprene and Tributyltin Methacrylate[J].Journal of Fujian Teachers University(Natural Science),1996,12(3):54-58.
Authors:Qian Qingrong  Wu Yuanhui
Institution:Experimental Center
Abstract:Graft copolymerization of tributyltin methacrylate onto neoprene wascarried out in benzene using benzoylperoxide as an initiator. The Neoprene-g-poly (tributyltin methacrylate)was isolated from the copolytnerization products by extracting with anhydrous alcohol.Percentage of grafting and grafting effeciency were calculated under different experimental condition.The copolymer was characterized by FT-IR and 1H-NMR. The results showed the occurrence of grafting.
Keywords:Neoprene  tributyltin methacrylate  copolymerization
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