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Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au (111) surface
作者姓名:CAO Liang  ZHANG WenHua  HAN YuYan  CHEN TieXin  ZHENG ZhiYuan  WAN Li  XU FaQiang  IBRAHIM Kurash  QIAN HaiJie  WANG JiaOu
作者单位:[1]National Synchrotron Radiation Laboratory, School of Nuclear Science and Technology, University of Science and Technology of China, Hefei 230029, China [2]Beijing Synchrotron Radiation Laboratory, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039, China
基金项目:supported by the National Natural Science Foundation of China (10975138, 10505019 and 10775126); the Scientific Research Foundation of the Graduate School of the University of Science and Technology of China
摘    要:The molecular orientation of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) multilayers adsorbed on Au (111) surface has been investigated using angular dependent O K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. The significant angular dependence of important resonant structures (π* and σ*) reveals that PTCDA molecules adopt an ordered geometry on the substrate surface. The average tilt angle of the PTCDA molecular planes is 27°±10° from the Au (111) surface.

关 键 词:NEXAFS  perylene-3  4  9  10-tetracarboxylic  acid  dianhydride  organic  electronics  molecular  orientation

Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au (111) surface
CAO Liang,ZHANG WenHua,HAN YuYan,CHEN TieXin,ZHENG ZhiYuan,WAN Li,XU FaQiang,IBRAHIM Kurash,QIAN HaiJie,WANG JiaOu.Angular dependent NEXAFS study of the molecular orientation of PTCDA multilayers on Au (111) surface[J].Chinese Science Bulletin,2011,56(33):3575-3577.
Authors:Liang Cao  WenHua Zhang  YuYan Han  TieXin Chen  ZhiYuan Zheng  Li Wan  FaQiang Xu  Kurash Ibrahim  HaiJie Qian  JiaOu Wang
Institution:CAO Liang1,ZHANG WenHua1,HAN YuYan1,CHEN TieXin1,ZHENG ZhiYuan1,WAN Li1,XU FaQiang1*,IBRAHIM Kurash2,QIAN HaiJie2 & WANG JiaOu2 1 National Synchrotron Radiation Laboratory,School of Nuclear Science and Technology,University of Science and Technology of China,Hefei 230029,China,2 Beijing Synchrotron Radiation Laboratory,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing 100039
Abstract:The molecular orientation of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) multilayers adsorbed on Au (111) surface has been investigated using angular dependent O K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. The significant angular dependence of important resonant structures (π* and σ*) reveals that PTCDA molecules adopt an ordered geometry on the substrate surface. The average tilt angle of the PTCDA molecular planes is 27°±10° from the Au (111) surface.
Keywords:NEXAFS  perylene-3  4  9  10-tetracarboxylic acid dianhydride  organic electronics  molecular orientation  
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