| 甲醛在聚苯胺载铂电极上的电催化氧化 |
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| 引用本文： | 陈忠平,褚道葆,秦家成,宋常春,汪徐春,陈君华,过家好,张婷.甲醛在聚苯胺载铂电极上的电催化氧化[J].吉林大学学报(理学版),2014,52(6):1331-1336. |
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| 作者姓名： | 陈忠平 褚道葆 秦家成 宋常春 汪徐春 陈君华 过家好 张婷 |
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| 作者单位： | 1. 安徽科技学院 化学与材料工程学院, 安徽 凤阳 233100;2. 安徽师范大学 化学与材料科学学院, 安徽 芜湖 241000; 3. 合肥工业大学 化工学院, 合肥 230009 |
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| 基金项目： | 国家自然科学基金，安徽省高校自然科学重点基金 |
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| 摘 要： | 通过电化学方法制备以金属钛为基体的聚苯胺载铂电极(Pt/PAn/Ti),并通过扫描电镜和循环伏安法对该电极进行表征.通过研究甲醛在该电极上的电催化氧化行为,考察该电极对甲醛的电催化氧化活性.结果表明:Pt/PAn/Ti电极对甲醛的电催化氧化作用与铂的沉积量有关;PAn的存在使得铂微粒分散程度更好,有效面积更大,与相同铂沉积量的Pt/Ti电极相比,甲醛在其上的正向扫描峰电流密度增加2.3倍,氧化峰电位负移40mV,反向扫描氧化峰电流密度增加5倍,氧化峰电位负移30mV;甲醛在Pt/PAn/Ti电极上正向扫描出现的氧化峰由液相传质过程控制,负向扫描的氧化峰由吸附行为控制.
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| 关 键 词： | 钛电极 聚苯胺 循环伏安法 电催化氧化 甲醛 |
| 收稿时间： | 2014-03-17 |
Electrocatalytic Oxidation of Formaldehyde on Platinum Load on Polyaniline Electrode |
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| CHEN Zhongping,CHU Daobao,QIN Jiacheng,SONG Changchun,WANG Xuchun,CHEN Junhua,GUO Jiahao,ZHANG Ting.Electrocatalytic Oxidation of Formaldehyde on Platinum Load on Polyaniline Electrode[J].Journal of Jilin University: Sci Ed,2014,52(6):1331-1336. |
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| Authors: | CHEN Zhongping CHU Daobao QIN Jiacheng SONG Changchun WANG Xuchun CHEN Junhua GUO Jiahao ZHANG Ting |
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| Institution: | 1. College of Chemistry and Material Engineering, Anhui Science and Technology University,Fengyang 233100, Anhui Province, China; 2. College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, Anhui Province, China;3. School of Chemical Engineering, Hefei University of Technology, Hefei 230009, China |
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| Abstract: | Polyaniline(PAn) was loaded on Ti based metal electrode and platinum was loaded on polyaniline, and Pt/PAn/Ti was preparedby cyclic voltammetry (CV) and was characterized by SEM and CV. Electrocatalyticoxidation of formaldehyde on platinum load on polyaniline electrode was investigated by reseaching the electrocatalytic oxidation of formaldehyde on Pt/PAn/Ti electrode. The result shows that electrocatalytic oxidation of formaldehyde was related with the quantity of platinum microparticles. Platinum microparticles were dispersed better, showing bigger effective area. Compared with that of the Pt/Ti electrode with the same quantity of platinum deposited, the peak current of formaldehyde in the positive scanning was increased 2.3 times and oxidation potential was negatively shifted by about 40 mV on Pt/PAn/Ti electrode. The peak current of formaldehyde in the negative scanning was increased about 5 times and oxidation potential was negatively shifted by about 30 mV. At the same time, the result shows, too that the oxidation peak in the positive scanning was controlled by liquid phase mass transfer process and the oxidation peak in the negative scanning was controlled by adsorption behavior. |
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| Keywords: | Ti electrode polyaniline cyclic voltammetry electrocatalytic oxidation formaldehyde |
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