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| 天然橡胶胶乳常压氢化的研究 | |
| 引用本文： | 潘勇军,罗武东,王云祥,陈克强,夏军,谢洪泉.天然橡胶胶乳常压氢化的研究[J].武汉科技学院学报,2005,18(4):33-35. |
| 作者姓名： | 潘勇军 罗武东 王云祥 陈克强 夏军 谢洪泉 |
| 作者单位： | 1. 武汉科技学院,环境与化学工程系,湖北,武汉,430073 2. 珠海出入境检验检疫局,广东,珠海,519015 3. 华中科技大学,化学系,湖北,武汉,430073 |
| 基金项目： | 湖北省教育厅重点项目(项目编号:2003A003). |
| 摘 要： | 用N2H4／H2O2／Cu^2 体系对天然橡胶胶乳进行了常压氢化试验。红外光谱表明，氢化过程中对应的双键的伸缩振动谱带的峰面积减少．天然橡胶产生了氢化．由红外光谱峰面积推算得到产物的最高氢化度为38％．产物的凝肢合量为1％。分析结果表明：高分子链双键被饱和后．形成聚乙烯链段而结晶，结晶起到了物理交联作用。 |
| 关 键 词： | 加氢 天然橡胶 肢乳 红外光谱 |
| 文章编号： | 1009-5160(2005)-0033-03 |
| 修稿时间： | 2005年3月20日 |
Study on Hydrogenated Nature Rubber from Nature Rubber Latex under Normal Pressure |
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| PAN Yong-jun,LUO Wu-dong,WANG Yun-xiang,CHENG Ke-qiang,XIA Jun,XIE Hong-quan.Study on Hydrogenated Nature Rubber from Nature Rubber Latex under Normal Pressure[J].Journal of Wuhan Institute of Science and Technology,2005,18(4):33-35. | |
| Authors: | PAN Yong-jun LUO Wu-dong WANG Yun-xiang CHENG Ke-qiang XIA Jun XIE Hong-quan |
| Institution: | PAN Yong-jun1,LUO Wu-dong2,WANG Yun-xiang1,CHENG Ke-qiang1,XIA Jun1,XIE Hong-quan3 |
| Abstract: | In this thesis, nature rubber latex was hydrogenated under normal pressure with N2H4/H2O2/Cu2+ system. The best reaction condition for the nature rubber was achieved. Hydrogenation degree and gel content of hydrogenated rubber reached about 38% and 1%. Microstructure and crystallization of HNR were characterized by IR. The result showed that rubber could be hydrogenated to form polyethylene segments which could crystallize to form physical crosslinkage. |
| Keywords: | Hydrogenation Nature Rubber Latex Infrared Spectra |
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