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Chenguodaite (Ag9FeTe2S4): a new tellurosulfide mineral from the gold district of East Shandong Peninsula,China
作者姓名:GU XiangPing  ;Makoto WATANABE  ;XIE XianDe  ;PENG ShengLin  ;Yoshihiro NAKAMUTA  ;Makio OHKAWA  ;Kenichi HOSHINO  ;Kazumasa OHSUMI  ;Yasuhiro SHIBATA
作者单位:[1]Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China; [2]Department of Earth & Planetary Sciences, Hiroshima University, Higashi Hiroshima City, Hiroshima 739-8526, Japan; [3]Department of Earth Sciences and Environmental Engineering, Central South University, Changsha 410083, China; [4]The Kyushu University Museum, Kyushu University, Kakozaki, Fukuoka 812-8581 Japan; [5]Photon Factory, National Laboratory for High Energy Physics (KEK), Oho 1-1, Tsukuba, Ibaraki 305, Japan
基金项目:Supported by National Natural Science Foundation of China (Grant No. 40572027)
摘    要:Chenguodaite, approved by IMA-CNMMN (2004-042a), was discovered in the Bunan quartz vein-type gold deposit in the gold district of East Shandong Peninsula. The mineral occurs in high grade Au-Ag-Cu ores, coexisting with galena, chalcopyrite, hessite, electrum, unnamed Ag6TeS2 and AglsFeBiTe3Se, enclosed and replaced by native silver and acanthite. In the reflected light microscope, the mineral has light gray color, indistinguishable anistropism and hardness around 2-3. The color indices of chenguodaite relative to ICE C illuminator are: x=0.3027, y=0.3076, Y=25.78%,λd=474 nm, Pe=3.68%, similar to those of canfieldite. The average chemical composition from 16 microprobe analyses is Ag8.97Fe1.00Te1.99S4.04, idealized to AggFeTe2S4. The polycrystalline X-ray diffraction of chenguodaite by Gandolfi camera and synchrotron oscillation photography results in 67 reflections with the 12 strongest being (relative intensity in bracket): 6.742(69), 6.416(39), 5.951(33), 3.265(100), 2.981(24), 2.649(22), 2.25(24), 2.188(71), 2.142(22), 2.123(31), 2.044(23), 1.949(33), which are indexed to a primitive orthorhombic cell with a=12.769 (2) A, b= 14.814(2) A, c= 16.233 (1) A, V= 3070.6 A^3, Z= 9, Dcal.=6.85 g/cm^3. The name is for the late Prof. Chen Guoda, a famous Chinese geologist and the founder of Diwa-Geodepression theory of tectonics.

关 键 词:Ag9FeTe2S4  新矿石  硫化亚碲  山东东部
收稿时间:2008-03-04
修稿时间:2008-05-14

Chenguodaite (Ag9FeTe2S4): a new tellurosulfide mineral from the gold district of East Shandong Peninsula, China
GU XiangPing,;Makoto WATANABE,;XIE XianDe,;PENG ShengLin,;Yoshihiro NAKAMUTA,;Makio OHKAWA,;Kenichi HOSHINO,;Kazumasa OHSUMI,;Yasuhiro SHIBATA.Chenguodaite (Ag9FeTe2S4): a new tellurosulfide mineral from the gold district of East Shandong Peninsula, China[J].Chinese Science Bulletin,2008,53(22):3567-3573.
Authors:XiangPing Gu  Makoto Watanabe  XianDe Xie  ShengLin Peng  Yoshihiro Nakamuta  Makio Ohkawa  Kenichi Hoshino  Kazumasa Ohsumi  Yasuhiro Shibata
Institution:1. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China
3. Department of Earth Sciences and Environmental Engineering, Central South University, Changsha, 410083, China
2. Department of Earth & Planetary Sciences, Hiroshima University, Higashi Hiroshima City, Hiroshima, 739-8526, Japan
4. The Kyushu University Museum, Kyushu University, Kakozaki, Fukuoka, 812-8581, Japan
5. Photon Factory, National Laboratory for High Energy Physics (KEK), Oho 1-1, Tsukuba, Ibaraki, 305, Japan
Abstract:Chenguodaite, approved by IMA-CNMMN (2004-042a), was discovered in the Bunan quartz vein-type gold deposit in the gold district of East Shandong Peninsula. The mineral occurs in high grade Au-Ag-Cu ores, coexisting with galena, chalcopyrite, hessite, electrum, unnamed Ag6TeS2 and Ag16FeBiTe3S8, enclosed and replaced by native silver and acanthite. In the reflected light microscope, the mineral has light gray color, indistinguishable anistropism and hardness around 2–3. The color indices of chenguodaite relative to ICE C illuminator are: x=0.3027, y=0.3076, Y=25.78%,-λd=474 nm, Pe=3.68%, similar to those of canfieldite. The average chemical composition from 16 microprobe analyses is Ag8.97Fe1.00Te1.99S4.04, idealized to Ag9FeTe2S4. The polycrystalline X-ray diffraction of chenguodaite by Gandolfi camera and synchrotron oscillation photography results in 67 reflections with the 12 strongest being (relative intensity in bracket): 6.742(69), 6.416(39), 5.951(33), 3.265(100), 2.981(24), 2.649(22), 2.25(24), 2.188(71), 2.142(22), 2.123(31), 2.044(23), 1.949(33), which are indexed to a primitive orthorhombic cell with a=12.769 (2) Å, b= 14.814(2) Å, c= 16.233 (1) Å, V= 3070.6 Å3, Z = 9, Dcal.=6.85 g/cm3. The name is for the late Prof. Chen Guoda, a famous Chinese geologist and the founder of Diwa-Geodepression theory of tectonics.
Keywords:chenguodaite  new mineral  tellurosulfide  synchrotron radiation  gold deposits  East Shandong
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