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| 绝对硬度参数在确定取代的乙烷构象中的应用 | |
| 引用本文： | 刘红星,崔建国,罗明武. 绝对硬度参数在确定取代的乙烷构象中的应用[J]. 广西师范学院学报(自然科学版), 1994, 0(2) |
| 作者姓名： | 刘红星 崔建国 罗明武 |
| 摘 要： | 本文通过Ｐｅａｒｓｏｎ提出的酸碱的绝对硬度参数（η）出发，假设取代的乙烷分子中两个相邻碳原子上所连接的基因之间存在某种吸引或排斥作用，定义出吸引参数ｆ，排斥参数，稳定参数ｋ，通过计算取代乙烷分子不同构象的ｋ值，可推断出该分子不同构象的稳定性大小。 |
| 关 键 词： | 构象，硬软酸碱原则，绝对硬度 |
The Application of Absolute Hardness Parameter to Determine the Conformations of Substituted Ethanes |
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| Liu Hongsing, Cui Jianguo, Luo Mingwu. The Application of Absolute Hardness Parameter to Determine the Conformations of Substituted Ethanes[J]. Journal of Guangxi Teachers Education University:Natural Science Edition, 1994, 0(2) | |
| Authors: | Liu Hongsing Cui Jianguo Luo Mingwu |
| Affiliation: | Department of Chemistry |
| Abstract: | According to the concept of absolute hardness pearson R. G. submitted, three parameters (Attractive parameter f, Repulsive parameter , stablized parameter k ) are designed by supposing that there is a kind of attraction or repulsion among groups bonded between two adjacent carbons. The stability of different conformers can be determined by calculating the k value of different conformations of substituted ethanes. |
| Keywords: | conformation principle of HSAB absolute hardness |
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