| 一些含锰铁或铁铁金属间键的有机化合物的合成和研究 |
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| 引用本文： | 李金山,张经坤.一些含锰铁或铁铁金属间键的有机化合物的合成和研究[J].南开大学学报,1996,29(4):99-100,105. |
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| 作者姓名： | 李金山 张经坤 |
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| 作者单位： | [1]南开大学元素有机化学研究所 [2]南开大学中心实验室 |
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| 摘 要： | 合成了５个含锰铁工铁铁金属间键的有机化合物ＬＭＦｅ（ＣＯ）２（Ｃ５Ｈ５）（Ｈ２Ｌ＝Ｔ（４－Ｒ）ＰＰ（四取代苯基叶啉）；Ｍ＝Ｍｎ，Ｒ＝Ｈ，Ｍｅ，ＭｅＯ，Ｍ＝Ｆｅ，Ｒ＝Ｈ，Ｃｌ），通过元素分析，红外光谱和穆斯堡尔谱对这些化合物进行了表征。结果表明除金属－金属键之外，在锰铁或铁铁之间还存在羰基桥。
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| 关 键 词： | 锰铁键 金属－金属键 金属有机化合物 铁铁键 |
SYNTHESIS AND INVESTIGATION OF SOME ORGANIC COMPOUNDS CONTAINING MANGANESE-IRON OR IRON-IRON BOND |
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| Li Jinshan.SYNTHESIS AND INVESTIGATION OF SOME ORGANIC COMPOUNDS CONTAINING MANGANESE-IRON OR IRON-IRON BOND[J].Acta Scientiarum Naturalium University Nankaiensis,1996,29(4):99-100,105. |
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| Authors: | Li Jinshan |
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| Abstract: | Five organic compounds containing manganese-iron or iron-iron bond, T(4-R)PPMFe(CO)2(C5H5)H2T(4-R)PP=tetra-substituted phenylporphine; M=Mn,R=H,Me,MeO;M=Fe,R=H,Cl],have been synthesized. These compounds have been characterized by elementary analysis,infrared spectrum and Moessbauer spectrum. The results indicated that there is a carbonyl bridge between manganese and iron or between iron and iron besides metal-metal bond. |
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| Keywords: | tatra-substituted phenylporphyrin coordination saturation Moessbauer spectrum |
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