| 不对称烯烃加成反应中的马氏规则和反马氏规则 |
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| 引用本文： | 沈丽丽,朱伯仲,宋连卿,郭书玲,田春丽. 不对称烯烃加成反应中的马氏规则和反马氏规则[J]. 河南教育学院学报(自然科学版), 2005, 14(4): 49-50 |
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| 作者姓名： | 沈丽丽 朱伯仲 宋连卿 郭书玲 田春丽 |
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| 作者单位： | 河南教育学院,化学系,河南,郑州,450014;河南工业大学,化学化工学院,河南,郑州,450052 |
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| 摘 要： | 从电子效应和反应历程两个方面探讨马氏规则；列举反马氏规则的几种类型，并加以解释．从中找出两者的内在联系，揭示马氏规则的本质。
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| 关 键 词： | 马氏规则 反马氏规则 电子效应 反应历程 碳正离子稳定性 |
| 文章编号： | 1007-0834(2005)04-0049-02 |
| 收稿时间： | 2005-09-26 |
| 修稿时间： | 2005-09-26 |
Markovnikov's Rule and Anti - Markovnikov's Rule in Addition Reaction to Unsymmetrical Alkenes |
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| SHEN Li-li,ZHU Bo-zhong,SONG Lian-qing,GUO Shu-ling,TIAN Chun-li. Markovnikov's Rule and Anti - Markovnikov's Rule in Addition Reaction to Unsymmetrical Alkenes[J]. Journal of Henan Education Institute(Natural Science Edition), 2005, 14(4): 49-50 |
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| Authors: | SHEN Li-li ZHU Bo-zhong SONG Lian-qing GUO Shu-ling TIAN Chun-li |
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| Affiliation: | a. The Department of Chemistry, Henan Institute of Education, Zhenzhou 450014, China ; b. The College of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450052, China |
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| Abstract: | Based on electron-effect and reaction mechanism,this article discusses Markovnikov's rule,lists several conditions anti-Markovnikov's rule and explains them.Inner connection was found in the two rules,and at the same time the essence of Markovnikov's rule was exploded. |
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| Keywords: | Markovnikov's rule anti-Markovnikov's rule electron-effect reaction mechanism Carbocation stabilization |
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