| 季_钅粦_盐相转移催化法制备高级氯代烷 |
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| 引用本文： | 杨光
,曾昭琼.季_钅粦_盐相转移催化法制备高级氯代烷[J].华南师范大学学报(自然科学版),1987,0(2):1. |
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| 作者姓名： | 杨光 曾昭琼 |
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| 摘 要： | 以九种季(钅粦)盐及三苯膦为催化剂合成正辛基氯,找出十六烷基三苯基溴化(钅粦)为较优的催化剂,并以它合成了四种氯代烷,结果较为满意.
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| 关 键 词： | 相转移催化 季(钅粦)盐 卡宾 合成 氯代烷 |
SYNTHESIS OF HIGHER ALKYL CHLORIDES THROUGH PTC OF PHOSPHONIUM SALTS |
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| Yang Guang Zeng Zhaoqiong.SYNTHESIS OF HIGHER ALKYL CHLORIDES THROUGH PTC OF PHOSPHONIUM SALTS[J].Journal of South China Normal University(Natural Science Edition),1987,0(2):1. |
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| Authors: | Yang Guang Zeng Zhaoqiong |
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| Institution: | Yang Guang Zeng Zhaoqiong |
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| Abstract: | N-Octyl chlorides has been synthesized with carbene method through PTC of nine phosphonium salts and Triphenylphos-phine. This shows that cetyltriphenyl -phosphonium bromide is a desirable catalyst. It helps satisfactorily produce the synthesis of four alkyl chlorides. |
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| Keywords: | phase transfer catalyst phosphonium salts carbene alkyl chlorides |
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