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Synthesis of 3-D ordered macroporous silicate using the template formed from monodispersed polystyrene latex
Authors:Kai Qi  Zhenzhong Yang  Lijun Wang  Zhengping Liu  Delu Zhao
Institution:(1) Polymer Physics Laboratory, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, China;(2) Department of Chemistry, Beijing Normal University, 100875 Beijing, China
Abstract:Based on the template formed from monodispersed polystyrene (PS) latex, a modified fast sol-gel process was employed to synthesize a three-dimensional (3-D) ordered macroporous silica material after removing the template by calcination at high temperature. It was indicated that there existed highly ordered packed pores within the whole silica material by SEM morphology observation. It was also found that the pores were interconnected. The pore size could be controlled mainly by varying the particle size of the latex ranging from 101 to 102 nm. The formation process of the ordered pores was also preliminarily discussed.
Keywords:monodispersed PS latex  fast sol-gel process  ordered macroporous material
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