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全光谱技术同时测定钐和钇
引用本文:王木林,曹世明.全光谱技术同时测定钐和钇[J].内蒙古大学学报(自然科学版),1997,28(2):192-195.
作者姓名:王木林  曹世明
作者单位:[1]内蒙古大学化学系 [2]内蒙古师范大学
摘    要:研究了偶氮氯磷-mA作显色剂,采用全光谱技术(付立叶域主组份分析)同时测定钐和钇。设计了两个名为SPAFA和SPFPCA的程序来进行计算。根据八个误差函数来推断因子数目。实验结果显示,本法对严重重叠的光谱是令人满意的。

关 键 词:全光谱技术      分光光度法  测定

Simultaneous Determination of Samarium and Yttrium by a Full Spectrum Technique
Wang Mulin,Liu Jin,Cao Shiming.Simultaneous Determination of Samarium and Yttrium by a Full Spectrum Technique[J].Acta Scientiarum Naturalium Universitatis Neimongol,1997,28(2):192-195.
Authors:Wang Mulin  Liu Jin  Cao Shiming
Institution:Wang Mulin 1 Liu Jin 1 Cao Shiming 2
Abstract:With a full spectrum technique,the principal component analysis in the fourier domain (FPCA) was studied for simultaneous determination of samarium and yttrium by chlorophosphonazo mA.Two computational programs called SPAFA and SPFPCA were designed to perform the calculations.Eight error functions were calculated for deducing the number of facotrs.Experimental results showed that these methods are successful even where there was severe overlap of spectra.
Keywords:a full spectrum technique  samarium  yttrium  spectrophotometric  principal component analysis
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