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Neutron activation analysis and Mössbauer spectroscopy research on coloring mechanism of Chinese Ru porcelain
Authors:Rongwu Li  Lei Yang  Guoxia Li  Weijuan Zhao  Zhengyao Gao  Jianzhong Xie  Jin Chen  Bin Zhang  Xinmin Sun  Songlin Feng  Xiuqin Jia  Song Han  Zhongxiang Huang
Affiliation:(1) Department of Physics, Beijing Normal University, 100875 Beijing, China;(2) Faculty of Physical Engineering, Zhengzhou University, 450052 Zhengzhou, China;(3) Faculty of English Language, Zhengzhou University, 450052 Zhengzhou, China;(4) Department of Architecture, Zhengzhou University, 450052 Zhengzhou, China;(5) Institute of Cultural Relic Archaeology of Henan Province, 450004 Zhengzhou, China;(6) Institute of High Energy Physics, Chinese Academy of Sciences, 100080 Beijing, China
Abstract:
The characteristic spectrum and its main wavelength of Ru porcelain glaze are measured by color difference instrument to determine the relations between glaze color and its main wavelength. The content of the 30 coloring elements in Ru porcelain is determined by neutron activation analysis (NAA), which showed that iron is the major coloring element. Mössbauer spectroscopy analysis shows that the iron element in the glaze exists in the form of structural iron (Fe2+, Fe3+). The quantitative relationship between the main wavelength of glaze in various colors and the relative content of structural iron (Fe2+/Fe3+) is determined. Thus the coloring mechanism of Ru porcelain is investigated entirely.
Keywords:Ru porcelain  characteristic spectrum  NAA  Mossbauer spectroscopy  coloring mechanism
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