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镍超细粒子催化2-丁醇液相脱氢反应动力学研究
引用本文:程祖毅,任家瑛.镍超细粒子催化2-丁醇液相脱氢反应动力学研究[J].华东师范大学学报(自然科学版),1994(4).
作者姓名:程祖毅  任家瑛
作者单位:华东师范大学化学系,上海电视大学医化系
摘    要:本文研究了镍超细粒子催化2-丁醇液相脱氢反应的动力学。研究表明:经活化处理的催化剂具有良好的催化性能,反应产物丁酮在催化剂表面吸附是阻碍反应进行的主要因素,其影响可通过速率方程定量说明,本文并对反应机理进行了探讨。

关 键 词:动力学,镍超细粒子,2-丁醇,脱氢反应

The Kinetics of Liquid Phase Dehydrogenation of 2-Butanol on Ni-Ultrafine Particle Catalyst
Chen Zhuyi, Ren Jiaying.The Kinetics of Liquid Phase Dehydrogenation of 2-Butanol on Ni-Ultrafine Particle Catalyst[J].Journal of East China Normal University(Natural Science),1994(4).
Authors:Chen Zhuyi  Ren Jiaying
Abstract:The kinetics of dehydrogenation of 2-butanol to butanone on Ni-Ultrafine particle catalyst has been studied. The results show that the activated catalysts have highly catalytic activity.Adsorption of reaction product Butanone on the catalyst surface was the main reason to decelerate the reaction. The effect has been described quantitatively by the equation. The reaction machanism was also discussed.
Keywords:kinetics Ni-ultrafine particls 2-butanol  dehydrogenation  
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