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泡腾颗粒药肥中除草剂的释放特性
引用本文:化全县,胡斌,汤建伟,刘咏,王立锁.泡腾颗粒药肥中除草剂的释放特性[J].科技导报(北京),2011,29(26):30-33.
作者姓名:化全县  胡斌  汤建伟  刘咏  王立锁
作者单位:1. 郑州大学化工与能源学院国家钙镁磷复合肥技术研究推广中心,郑州 450001;2. 中国科学院南京土壤研究所土壤与农业可持续发展国家重点实验室,南京 210008
摘    要: 为提高颗粒药肥中除草剂的释放性能,制备了具有泡腾特性的除草药肥颗粒,以亚甲基蓝比色法评价其泡腾特性,研究了除草药肥颗粒中苯噻酰草胺和苄嘧磺隆的释放过程.结果表明,颗粒药肥具有显著的泡腾作用,苯噻酰草胺和苄嘧磺隆释放平衡时间为15和11min,仅为传统型颗粒药肥的33.3%和36.7%.两种除草剂的释放过程均遵循双常数方程和Logistic方程,且相关性达到极显著水平(P<0.001),释放速率由液膜扩散和颗粒内扩散联合控制.

关 键 词:颗粒药肥  泡腾  苯噻酰草胺  苄嘧磺隆  释放动力学  
收稿时间:2011-06-03

Release Kinetics of Herbicide in Fertilizer-herbicide Granules with Effervescent Characteristics
HUA Quanxian,HU Bin,TANG Jianwei,LIU Yong,WANG Lisuo.Release Kinetics of Herbicide in Fertilizer-herbicide Granules with Effervescent Characteristics[J].Science & Technology Review,2011,29(26):30-33.
Authors:HUA Quanxian  HU Bin  TANG Jianwei  LIU Yong  WANG Lisuo
Institution:1. National Centre of Research & Popularization on Calcium, Magnesium, Phosphate and Compound Fertilizer Technology, School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;2. State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
Abstract:The fertilizer-herbicide granule with effervescent agent coating was prepared to increase the herbicide release rate. The effervescency of the granule enjoys a remarkable performance, which was evaluated with the methylene blue spectrophotometric method. The experiments revealed the release kinetics of mefenacet and bensulfuron-methyl (BSM) in the granule. The results show that the release equilibration time of mefenacet and bensulfuron-methyl in the effervescent granule is 15 and 11min, respectively, 33.3% and 36.7% of that in the common fertilizer-herbicide granule. The release kinetics of mefenacet and bensulfuron-methyl follows the dual constant equation and Logistic equation, with a correlation coefficients highly significant (P< 0.001). Their release rates are controlled by the Boyd film diffusion model and the Kannan-Sundaram intraparticle diffusion one.
Keywords:fertilizer-herbicide granule  effervescent  mefenacet  bensulfuron-methyl  release kinetics  
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