| 废轮胎热解油轻质馏分加氢脱硫反应的本征动力学 |
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| 引用本文： | 余锋,邹滢,王慧,翁惠新.废轮胎热解油轻质馏分加氢脱硫反应的本征动力学[J].华东理工大学学报(自然科学版),2011,37(2):145-150. |
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| 作者姓名： | 余锋 邹滢 王慧 翁惠新 |
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| 作者单位： | 华东理工大学石油加工研究所,上海,200237 |
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| 摘 要： | 采用微型固定床反应装置,选用FH-98型催化剂,在催化剂活性稳定阶段且消除内、外扩散影响的情况下,进行废轮胎热解油轻质馏分加氢脱硫反应本征动力学研究,并考察了反应温度(563.15-643.15K)、反应压力(1.0-3.0MPa)对加氢脱硫反应的影响规律.结果表明:提高反应温度和反应压力对加氢脱硫反应有利;经F检验及...
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| 关 键 词： | 废轮胎热解油 轻质馏分 加氢脱硫 本征动力学 |
Intrinsic Kinetics of Hydrodesulfurization of Light Fraction of Used Tire Pyrolysis Oil |
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| YU Feng,ZOU Ying,WANG Hui,WENG Hui-xin.Intrinsic Kinetics of Hydrodesulfurization of Light Fraction of Used Tire Pyrolysis Oil[J].Journal of East China University of Science and Technology,2011,37(2):145-150. |
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| Authors: | YU Feng ZOU Ying WANG Hui WENG Hui-xin |
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| Institution: | YU Feng,ZOU Ying,WANG Hui,WENG Hui-xin(Petroleum Processing Research Center,East China University of Science and Technology,Shanghai 200237,China) |
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| Abstract: | Intrinsic kinetics of hydrodesulfurization(HDS) of light fraction of used tire pyrolysis oil over the FH-98 catalyst was studied in a micro-fixed bed reactor during the stage with stable catalyst activity and without internal and external diffusion.The effects of reaction temperature(563.15-643.15 K) and reaction pressure(1.0-3.0 MPa) on HDS were investigated.The results showed that the increase of reaction temperature and pressure was favorable to the HDS reaction.The kinetic model was significantly reliab... |
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| Keywords: | used tire pyrolysis oil light fraction hydrodesulfurization intrinsic kinetics |
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