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沉积物和生物膜吸附阿特拉津的灰色关联分析
引用本文:李鱼,王倩,高茜,王岙.沉积物和生物膜吸附阿特拉津的灰色关联分析[J].江苏大学学报(自然科学版),2012,33(2):223-227.
作者姓名:李鱼  王倩  高茜  王岙
作者单位:1. 华北电力大学能源与环境研究院,北京102206;华北电力大学区域能源系统优化教育部重点实验室,北京102206
2. 吉林大学环境与资源学院,吉林长春,130012
基金项目:国家自然科学基金资助项目(50879025)
摘    要:借助灰色关联度筛选出复合污染体系Cd2+/AT,Cu2 +/AT中沉积物和生物膜吸附阿特拉津(AT)的主要吸附位,包括活性组分铁氧化物(Fe)、锰氧化物(Mn)、有机质(OMs)及其交互作用,并建立主要吸附位与AT吸附量的多元线性回归模型.多元线性回归模型结果表明:Cd2+对AT的吸附表现为协同作用,Cd2+质量浓度为0.2mg·L-1时协同效应最显著;Cu2对AT的吸附表现为拮抗作用,抑制效应随Cu2+质量浓度增大呈逐渐增强趋势.Cd2+,Cu2+显著影响了活性组分及其交互作用对AT的吸附行为,活性组分之间的交互作用在AT迁移转化方面发挥着至关重要的作用.

关 键 词:表层沉积物  生物膜  重金属  阿特拉津  灰色关联度  复合污染  交互作用

Gray relation analysis of atrazine adsorption onto surficial sediments and natural surficial coating samples
Li Yu , Wang Qian , Gao Qian , Wang Ao.Gray relation analysis of atrazine adsorption onto surficial sediments and natural surficial coating samples[J].Journal of Jiangsu University:Natural Science Edition,2012,33(2):223-227.
Authors:Li Yu  Wang Qian  Gao Qian  Wang Ao
Institution:1.Research Academy of Energy and Environmental Studies,North China Electric Power University,Beijing 102206,China;2.Key Laboratory of Regional Energy Systems Optimization of Ministry of Education,North China Electric Power University,Beijing 102206,China;3.College of Environment and Resources,Jilin University,Changchun,Jilin 130012,China)
Abstract:The main sites of atrazine(AT) adsorption onto the surficial sediments and natural surficial coating samples in Cd2+/AT,Cu2+/AT composite contamination systems were filtrated according to gray correlation of the active fractions of Fe oxides,Mn oxides,organic materials and their interactions.A multiple regression model between AT adsorption amount and main adsorption sites was established.The results show that Cd2+ expresses synergetic effect on AT adsorption with the most significant efficiency at Cd2+ level of 0.2 mg·L-1.The antagonistic effect caused by Cu2+ on AT adsorption is generally enhanced by the increasing of Cu2+ levels.Cd2+ or Cu2+ can dramatically influence active fractions and their interactions on AT adsorption.The interactions among active fractions play an important role in controlling the environmental behaviors of AT in aquatic environments.
Keywords:surficial sediments  natural surficial coating samples  heavy metals  atrazine  grey correlation  composite contamination  interactions
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