| 铈钴复合氧化物的制备及表征 |
| |
| 引用本文： | 王宝罗,方卫民. 铈钴复合氧化物的制备及表征[J]. 南京师大学报(自然科学版), 2007, 30(1): 53-56 |
| |
| 作者姓名： | 王宝罗 方卫民 |
| |
| 作者单位： | 盐城师范学院化学系 江苏盐城224002(王宝罗)，浙江大学西溪校区化学系 浙江杭州310028(方卫民) |
| |
| 摘 要： | 以硝酸钴和硝酸铈、EDTA等为基本原料,采用水热合成法制备出前驱体,前驱体经高温煅烧获得铈钴复合氧化物粉体.然后运用TG-DTA、XRD、SEM、FT-IR等检测手段对前驱体及产物的物性和结构进行表征,结果表明:在本实验条件下,前驱体具有一定的抗烧结能力;高温时CeO2的XRD衍射峰峰位向小角度移动,钴元素已掺入到CeO2的晶格之中,形成了铈钴复合氧化物,是一种优良的软磁性材料.
|
| 关 键 词： | 水热合成 铈钴复合 氧化物 软磁性 复合氧化物 表征 Complex Oxide Cobalt Cesium Characterization 磁性材料 晶格 掺入 钴元素 移动 小角度 位向 峰峰 衍射 高温时 抗烧结能力 实验条件 结果 结构 |
| 文章编号： | 1001-4616（2007）01-0053-04 |
| 收稿时间： | 2005-09-28 |
| 修稿时间： | 2005-12-06 |
Preparation and Characterization of Cesium and Cobalt Complex Oxide |
| |
| Wang Baoluo,Fang Weimin. Preparation and Characterization of Cesium and Cobalt Complex Oxide[J]. Journal of Nanjing Normal University(Natural Science Edition), 2007, 30(1): 53-56 |
| |
| Authors: | Wang Baoluo Fang Weimin |
| |
| Affiliation: | 1. Department of Chemistry, Yancheng Teachers College, Yancheng 224002, China;2. Department of Chemistry of Xixi Campus, Zhejiang University, Hangzhou 310028, China |
| |
| Abstract: | The predecessor bulk is made from the elementary crude material such as cobalt nitrate,EDTA and so on,with the method of hydro-thermal synthesis.Then the predecessor is formed into the compound oxide of cobalt and cesium after incineration at high temperature.The physical property and structure of the predecessor bulk and product can be detected by some methods,for example TG-DTA,XRD,SEM and so on.The result indicates that the predecessor bulk has the ability of resistance to agglomeration in the condition of the experiment.At the high temperature,the peak of XRD diffraction maximum moves towards a small angle.So the cobalt element is doped into the crystal lattice of CeO2,and nanometer compound oxide of cobalt and cesium is formed.It is a good soft magnetic material. |
| |
| Keywords: | hydro-thermal synthesis compound oxide of cobalt and cesium nanometer soft magnetism |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
