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改性硅藻土对重金属离子的吸附规律
引用本文:杨婷,王洪良,吕春欣,熊鹰,何冲,康春莉.改性硅藻土对重金属离子的吸附规律[J].吉林大学学报(理学版),2012,50(4):815-821.
作者姓名:杨婷  王洪良  吕春欣  熊鹰  何冲  康春莉
作者单位:吉林大学 环境与资源学院, 长春 130012
摘    要: 利用CaCO3对硅藻土矿物进行改性. 研究结果表明: 单组分体系中CaCO3改性的硅藻土对Cu2+,Pb2+,Cd2+和Zn2+的吸附动力学规律均符合伪二阶动力学模型, 吸附热力学规律符合Langmuir模型; 在混合组分体系中, Pb2+,Cd2+和Zn2+的吸附速率降低, Cu2+的吸附速率增加, 对金属离子的吸附动力学规律仍然符合伪二阶动力学模型, 但对金属离子的吸附量均明显降低, 仅Pb2+的吸附热力学规律符合Langmuir模型.

关 键 词:,硅藻土,改性,重金属,吸附,

Adsorption Law of Heavy Metals on Modified Diatomite
YANG Ting , WANG Hong-liang , L Chun-xin , XIONG Ying , HE Chong , KANG Chun-li.Adsorption Law of Heavy Metals on Modified Diatomite[J].Journal of Jilin University: Sci Ed,2012,50(4):815-821.
Authors:YANG Ting  WANG Hong-liang  L Chun-xin  XIONG Ying  HE Chong  KANG Chun-li
Institution:College of Environment and Resources, Jilin University, Changchun 130012, China
Abstract:Rich low-grade diatomite mineral was modified with calcium carbonate so as to improve the adsorption properties of diatomite for heavy metal ions.The results show that in a single component system,the dynamic laws for the adsorption of Cu2+,Pb2+,Cd2+and Zn2+ on the diatomite modified by calcium carbonate obey the pseudo-second-order model and the adsorption thermodynamics laws obey the Langmuir model.In a mixed component system,because of the effect of coexisting components,the adsorption rate of Pb2+,Cd2+ and Zn2+ was decreased respectively and the adsorption rate of Cu2+ was increased,but the adsorption dynamic laws of four kinds of metal ions still obey the pseudo-second-order model;at the same time,the adsorption capacities of four kinds of metal ions on the modified diatomite were decreased obviously and only the adsorption thermodynamics law of Pb2+ obeys the Langmuir model.
Keywords:diatomite  modified  heavy metals  adsorption
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