| Synthesis,Structural Characterization,and Electrochemical Properties of Binuclear Copper(Ⅱ) Complexes Containing Tetradentate Schiff Base Ligand |
| |
| 基金项目： | Supported by the Project for Distinguished Young Scholars from Hubei Provincial Department of Education (Q20082601) |
| |
| 摘 要： | Two binuclear copper(Ⅱ) complexes, Cu2(saloph)2 (μ-O)2]-2(DMF)H2saloph=N,N′-o-phenylenebis(salicylideneaminato)] (a) and Cu2(salen)2(μ-O)2] H2salen=N,N′-bis(salicylic-deneaminato) ethylene] (b)were synthesized and characterized by X-ray crystallography. Both of them have distorted rectangular pyramidal geometry around Cu(Ⅱ). The complete series of complexes show bridging phenoxo groups between the copper centers, together with hydroxo-bridges in these complexes. The complexes have also been characterized by elemental analysis, IR, TG-DTA, and electrochemical results.
|
| 关 键 词： | copper(Ⅱ) complexes crystal structure electrochemical properties |
Synthesis,structural characterization,and electrochemical properties of binuclear copper(II) complexes containing tetradentate Schiff base ligand |
| |
| Authors: | Yu Ding Xiaoxia Hu Xiaoli Sun Zhiling Zuo |
| |
| Institution: | DING Yu,HU Xiaoxia,SUN Xiaoli,ZUO Zhiling School of Chemistry , Materials Science,Xiaogan University,Xiaogan 432000,Hubei,China |
| |
| Abstract: | Two binuclear copper (II) complexes, Cu2(saloph)2(μ-O)2]·2(DMF)H2saloph=N,N′-o-phenylenebis(salicylideneaminato)](a) and Cu2(salen)2(μ-O)2] H2salen=N,N′-bis(salicylic-deneaminato) ethylene] (b)were synthesized and characterized by X-ray crystallography. Both of them
have distorted rectangular pyramidal geometry around Cu(II). The complete series of complexes show bridging phenoxo groups
between the copper centers, together with hydroxo-bridges in these complexes. The complexes have also been characterized by
elemental analysis, IR, TG-DTA, and electrochemical results. |
| |
| Keywords: | |
| 本文献已被 CNKI SpringerLink 等数据库收录！ |
|
