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改性纳米二氧化硅用于丙烯酸聚氨酯防腐涂料
引用本文:陈颖敏,侯玉婧,俞立.改性纳米二氧化硅用于丙烯酸聚氨酯防腐涂料[J].河北大学学报(自然科学版),2012,32(6):613-618.
作者姓名:陈颖敏  侯玉婧  俞立
作者单位:华北电力大学环境与科学工程学院,河北保定,071003
摘    要:为改善纳米二氧化硅的分散性,以硅烷偶联剂KH-570,分散剂BYK-163和钛酸酯偶联剂NDZ-201对纳米二氧化硅进行表面改性.通过沉降率、FTIR和SEM等表征评定方法,对产物结构和性能进行了分析.结果表明,KH570能够对二氧化硅进行改性,并且效果优良.最佳改性条件为:改性剂用量为5%,反应时间30min左右,改性后的纳米二氧化硅用于丙烯酸聚氨酯防腐涂料中,涂料各项性能都有较大改善,均达到国家标准.

关 键 词:纳米二氧化硅  表面改性  硅烷偶联剂KH570  丙烯酸聚氨酯涂料

Modified silica nanoparticles for acrylic polyurethane coating
CHEN Yingmin , HOU Yujing , YU Li.Modified silica nanoparticles for acrylic polyurethane coating[J].Journal of Hebei University (Natural Science Edition),2012,32(6):613-618.
Authors:CHEN Yingmin  HOU Yujing  YU Li
Institution:(School of Environmental Science&Engineering,North China Electric Power University,Baoding 071003,China)
Abstract:In order to improve the dispersion of nano silica,the surface modification of nano silica was modified by silane coupling agent KH-570,BYK-163 dispersant and titanate coupling agent NDZ-201.Through the sedimentation rate,FTIR and SEM characterization evaluation method,the structure of the product and performance are analysed.The experimental results indicate that the performance of the KH-570 is the best,coupling agent amout is 5%,reaction time is about 30 minutes.Modified nano-silica for acrytic polyurethane anti-corrosion coatings,paints the performance has greatly improved and reached the national standard.
Keywords:SiO2 nanoparticles  surface modification  silane coupling agent KH570  acrylic polyurethane coatings
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