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无熟料高炉矿渣水泥的物料配比与性能的关系
引用本文:张明涛,谭克锋,赵敏.无熟料高炉矿渣水泥的物料配比与性能的关系[J].西南科技大学学报,2011,26(2).
作者姓名:张明涛  谭克锋  赵敏
作者单位:西南科技大学材料科学与工程学院,四川绵阳,621010
基金项目:四川省教育厅项目(10zd1104)
摘    要:研究了Ca(OH)_2、硬石膏及少量可溶性钙盐(甲酸钙、乙酸钙等)复合对高炉矿渣活性的激发作用及物料配比与性能的关系。结果表明:Ca(OH)_2与硬石膏复合对矿渣活性有一定的激发效果,可溶性钙盐的加入降低了水泥的pH值,进一步激发了矿渣的活性,乙酸钙(Ca(CH_2COOH)_2)的激发效果好于甲酸钙(Ca(COOH)_2);在矿渣掺量为80%,Ca(OH)_2掺量15%,硬石膏掺量5%,外加1.0%Ca(CH_2COOH)_2生产出的无熟料水泥28 d抗压强度达54.6 MPa;Ca(COOH)_2与硬石膏促进高炉矿渣水化的主要水化产物为钙矾石和C-S-H凝胶。

关 键 词:无熟料高炉矿渣水泥  硬石膏  可溶性钙盐  激发剂  

Research on the Proportioning and Performance of Non-clinker Blast Furnace Slag Cement
ZHANG Ming-tao,TAN Ke-feng,ZHAO Min.Research on the Proportioning and Performance of Non-clinker Blast Furnace Slag Cement[J].Journal of Southwest University of Science and Technology,2011,26(2).
Authors:ZHANG Ming-tao  TAN Ke-feng  ZHAO Min
Institution:ZHANG Ming-tao,TAN Ke-feng,ZHAO Min (School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang 621010,Sichuan,China)
Abstract:The activating effect of blast furnace slag under the activation of Ca(OH)_2,CaSO_4,and some soluble calcium salts(calcium formate,calcium acetate) was investigated,as well as the relation between material proportion and property.The results show that Ca(OH)_2 combined with CaSO_4 increases the activity of slag significantly.The lowing of pH caused by the addition of soluble calcium can further stimulate the activeness of slag.Comparably,the effect of Ca(CH_2COOH)_2 is better than Ca(COOH)_2 to stimulate th...
Keywords:Non-clinker blast furnace slag cement  CaSO_4  Soluble calcium salts  Activating Agent  
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