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1:6结构的杂多酸盐掺杂聚苯胺的固相合成及荧光性质
引用本文:李书鹏,殷广明,李春晖.1:6结构的杂多酸盐掺杂聚苯胺的固相合成及荧光性质[J].齐齐哈尔大学学报(自然科学版),2007,23(2):13-15.
作者姓名:李书鹏  殷广明  李春晖
作者单位:1. 齐齐哈尔大学化工学院,黑龙江,齐齐哈尔,161006
2. 齐齐哈尔实验中学,黑龙江齐齐哈尔,161006
摘    要:采用固相反应法制备了1:6结构杂多阴离子掺杂的聚苯胺材料,运用FT-IR、XRD进行了表征;荧光光谱表明掺杂材料在426 nm、570 nm有较好的荧光发射峰;掺杂材料在N,N-二甲基乙酰胺(DMF)中有较好的溶解度,最高导电率为2.8×10-2S.cm-1。

关 键 词:1:6结构杂多酸  掺杂  聚苯胺  荧光
文章编号:1007-984X(2007)02-0013-03
修稿时间:2006-12-26

Solid-state synthesis,characterization and fluorescence properties of Polyaniline doped with 1:6 structure Heteropolyacid
Li ShuPeng,Yin GuangMing,Li ChunHui.Solid-state synthesis,characterization and fluorescence properties of Polyaniline doped with 1:6 structure Heteropolyacid[J].Journal of Qiqihar University(Natural Science Edition),2007,23(2):13-15.
Authors:Li ShuPeng  Yin GuangMing  Li ChunHui
Institution:1.School of Chemistry and Chemical Engineering,Qiqihar University,Heilongjiang Qiqihar 16106,China; 2. Shiyan High School of Qiqihar, Heilongjiang Qiqihar 16106,China
Abstract:The materials of Polyaniline doped with XMo6O24H6]3(4)-(X=Cr,Zn,Ni) were prepared by solid-state synthesis methodt,he materials were characterized by FT-IR,XRD;Fluorescence properties,conductivity,solubility in different solvents were determined.The fluorescence properties showed that there were fluorescence emission band at 426 nm and 570 nm.
Keywords:1:6 structure Heteropolyacid  Dope  Polyaniline  Fluorescence
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